Research output: Contribution to journal › Article › peer-review
Interfacial interactions and interfacial polarization in polyazomethine/MWCNTs nanocomposites. / Bronnikov, Sergei; Kostromin, Sergei; Asandulesa, Mihai; Pankin, Dmitrii; Podshivalov, Aleksandr.
In: Composites Science and Technology, Vol. 190, 108049, 12.04.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Interfacial interactions and interfacial polarization in polyazomethine/MWCNTs nanocomposites
AU - Bronnikov, Sergei
AU - Kostromin, Sergei
AU - Asandulesa, Mihai
AU - Pankin, Dmitrii
AU - Podshivalov, Aleksandr
N1 - Funding Information: The authors acknowledge the Center for Optical and Laser Materials Research, Research Park, St. Petersburg State University, for Raman spectra performance and Dr. M. Sokolova, Institute of Macromolecular Compounds, for providing the AFM images. Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/4/12
Y1 - 2020/4/12
N2 - We prepared the polyazomethine/MWCNTs nanocomposites varying in the nanofiller loading (from 0 to 1.5 wt%). Taking into account an upshift of the characteristic D and G bands of MWCNTs in the Raman spectrum of the nanocomposite, we confirmed the interfacial interactions between MWCNTs and polymer chains. When we studied the nanocomposites morphology, we concluded that both disentanglement and dispersion of MWCNTs in the polymer matrix are provided by interfacial interactions. Using broadband dielectric spectroscopy technique, we investigated the interfacial polarization in the nanocomposites. We found that this phenomenon is valuable for electrical conductivity of the nanocomposites with high MWCNTs loading, particularly, at high temperatures and low frequencies.
AB - We prepared the polyazomethine/MWCNTs nanocomposites varying in the nanofiller loading (from 0 to 1.5 wt%). Taking into account an upshift of the characteristic D and G bands of MWCNTs in the Raman spectrum of the nanocomposite, we confirmed the interfacial interactions between MWCNTs and polymer chains. When we studied the nanocomposites morphology, we concluded that both disentanglement and dispersion of MWCNTs in the polymer matrix are provided by interfacial interactions. Using broadband dielectric spectroscopy technique, we investigated the interfacial polarization in the nanocomposites. We found that this phenomenon is valuable for electrical conductivity of the nanocomposites with high MWCNTs loading, particularly, at high temperatures and low frequencies.
KW - Interfacial interactions
KW - Interfacial polarization
KW - Polyazomethine/MWCNTs nanocomposites
KW - MATRIX
KW - METHODOLOGY
KW - DESIGN
KW - RELAXATION PROCESSES
KW - ELECTRICAL-CONDUCTIVITY
KW - DIELECTRIC PERMITTIVITY
KW - CARBON NANOTUBES
UR - http://www.scopus.com/inward/record.url?scp=85078844818&partnerID=8YFLogxK
U2 - 10.1016/j.compscitech.2020.108049
DO - 10.1016/j.compscitech.2020.108049
M3 - Article
AN - SCOPUS:85078844818
VL - 190
JO - Composites Science and Technology
JF - Composites Science and Technology
SN - 0266-3538
M1 - 108049
ER -
ID: 70199106