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Interaction potentials of Hg* plus He at moderate interatomic separations and the radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms. / Devdariani, AZ; Zagrebin, AL; Lednev, MG; Alekseyev, AB; Liebermann, HP; Buenker, RJ.

In: OPTICS AND SPECTROSCOPY, Vol. 91, No. 6, 12.2001, p. 833-841.

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Devdariani, AZ ; Zagrebin, AL ; Lednev, MG ; Alekseyev, AB ; Liebermann, HP ; Buenker, RJ. / Interaction potentials of Hg* plus He at moderate interatomic separations and the radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms. In: OPTICS AND SPECTROSCOPY. 2001 ; Vol. 91, No. 6. pp. 833-841.

BibTeX

@article{3e9c8bba7caa477e8276bef2568eb320,
title = "Interaction potentials of Hg* plus He at moderate interatomic separations and the radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms",
abstract = "By using the modified method of the Fermi pseudopotential and the effective Hamiltonian method, a multiconfiguration calculation of the potential curves is performed for the Hg(6(1,3)P(J)) + He and Hg(7(1,3)S(J)) + He interactions in the region of interatomic separations R greater than or equal to 5a(0). In this calculation, the interactions of different excited configurations and the spin-orbit coupling of singlet and triplet states were taken into account. The Hg+ + He ion-atom interaction potential was obtained by the nonempirical configuration interaction method MRD-CI with the use of the relativistic effective core potential (RECP) for the Hg atom. Based on the calculated potential curves and the transition dipole moments, the process of radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms is considered and the temperature dependence of the rate constant is calculated. (C) 2001 MAIK {"}Nauka/Interperiodica{"}.",
keywords = "ORBIT CONFIGURATION-INTERACTION, EFFECTIVE CORE POTENTIALS, ELECTRONIC WAVE-FUNCTIONS, DER-WAALS COMPLEXES, CI CALCULATIONS, PROBABILITIES, TRANSITIONS, MOLECULES, CURVES, VAPOR",
author = "AZ Devdariani and AL Zagrebin and MG Lednev and AB Alekseyev and HP Liebermann and RJ Buenker",
year = "2001",
month = dec,
doi = "10.1134/1.1429692",
language = "Английский",
volume = "91",
pages = "833--841",
journal = "OPTICS AND SPECTROSCOPY",
issn = "0030-400X",
publisher = "Pleiades Publishing",
number = "6",

}

RIS

TY - JOUR

T1 - Interaction potentials of Hg* plus He at moderate interatomic separations and the radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms

AU - Devdariani, AZ

AU - Zagrebin, AL

AU - Lednev, MG

AU - Alekseyev, AB

AU - Liebermann, HP

AU - Buenker, RJ

PY - 2001/12

Y1 - 2001/12

N2 - By using the modified method of the Fermi pseudopotential and the effective Hamiltonian method, a multiconfiguration calculation of the potential curves is performed for the Hg(6(1,3)P(J)) + He and Hg(7(1,3)S(J)) + He interactions in the region of interatomic separations R greater than or equal to 5a(0). In this calculation, the interactions of different excited configurations and the spin-orbit coupling of singlet and triplet states were taken into account. The Hg+ + He ion-atom interaction potential was obtained by the nonempirical configuration interaction method MRD-CI with the use of the relativistic effective core potential (RECP) for the Hg atom. Based on the calculated potential curves and the transition dipole moments, the process of radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms is considered and the temperature dependence of the rate constant is calculated. (C) 2001 MAIK "Nauka/Interperiodica".

AB - By using the modified method of the Fermi pseudopotential and the effective Hamiltonian method, a multiconfiguration calculation of the potential curves is performed for the Hg(6(1,3)P(J)) + He and Hg(7(1,3)S(J)) + He interactions in the region of interatomic separations R greater than or equal to 5a(0). In this calculation, the interactions of different excited configurations and the spin-orbit coupling of singlet and triplet states were taken into account. The Hg+ + He ion-atom interaction potential was obtained by the nonempirical configuration interaction method MRD-CI with the use of the relativistic effective core potential (RECP) for the Hg atom. Based on the calculated potential curves and the transition dipole moments, the process of radiative decay of the Hg(6 P-3(2)) metastable state in collisions with He atoms is considered and the temperature dependence of the rate constant is calculated. (C) 2001 MAIK "Nauka/Interperiodica".

KW - ORBIT CONFIGURATION-INTERACTION

KW - EFFECTIVE CORE POTENTIALS

KW - ELECTRONIC WAVE-FUNCTIONS

KW - DER-WAALS COMPLEXES

KW - CI CALCULATIONS

KW - PROBABILITIES

KW - TRANSITIONS

KW - MOLECULES

KW - CURVES

KW - VAPOR

U2 - 10.1134/1.1429692

DO - 10.1134/1.1429692

M3 - статья

VL - 91

SP - 833

EP - 841

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 6

ER -

ID: 74050584