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Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. / Moiseev, Mikhail M.; Panikorovskii, Taras L.; Aksenov, Sergey M.; Mazur, Anton S.; Mikhailova, Julia A.; Yakovenchuk, Victor N.; Bazai, Ayya V.; Ivanyuk, Gregory Yu; Agakhanov, Atali A.; Shilovskikh, Vladimir V.; Pekov, Igor V.; Kasatkin, Anatoly V.; Rusakov, Vyacheslav S.; Yapaskurt, Vasiliy O.; Karpenko, Vladimir Yu; Krivovichev, Sergey V.

In: Physics and Chemistry of Minerals, Vol. 47, No. 3, 18, 22.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Moiseev, MM, Panikorovskii, TL, Aksenov, SM, Mazur, AS, Mikhailova, JA, Yakovenchuk, VN, Bazai, AV, Ivanyuk, GY, Agakhanov, AA, Shilovskikh, VV, Pekov, IV, Kasatkin, AV, Rusakov, VS, Yapaskurt, VO, Karpenko, VY & Krivovichev, SV 2020, 'Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration', Physics and Chemistry of Minerals, vol. 47, no. 3, 18. https://doi.org/10.1007/s00269-020-01086-7

APA

Moiseev, M. M., Panikorovskii, T. L., Aksenov, S. M., Mazur, A. S., Mikhailova, J. A., Yakovenchuk, V. N., Bazai, A. V., Ivanyuk, G. Y., Agakhanov, A. A., Shilovskikh, V. V., Pekov, I. V., Kasatkin, A. V., Rusakov, V. S., Yapaskurt, V. O., Karpenko, V. Y., & Krivovichev, S. V. (2020). Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. Physics and Chemistry of Minerals, 47(3), [18]. https://doi.org/10.1007/s00269-020-01086-7

Vancouver

Moiseev MM, Panikorovskii TL, Aksenov SM, Mazur AS, Mikhailova JA, Yakovenchuk VN et al. Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. Physics and Chemistry of Minerals. 2020 Feb 22;47(3). 18. https://doi.org/10.1007/s00269-020-01086-7

Author

Moiseev, Mikhail M. ; Panikorovskii, Taras L. ; Aksenov, Sergey M. ; Mazur, Anton S. ; Mikhailova, Julia A. ; Yakovenchuk, Victor N. ; Bazai, Ayya V. ; Ivanyuk, Gregory Yu ; Agakhanov, Atali A. ; Shilovskikh, Vladimir V. ; Pekov, Igor V. ; Kasatkin, Anatoly V. ; Rusakov, Vyacheslav S. ; Yapaskurt, Vasiliy O. ; Karpenko, Vladimir Yu ; Krivovichev, Sergey V. / Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. In: Physics and Chemistry of Minerals. 2020 ; Vol. 47, No. 3.

BibTeX

@article{a3528041e737476a8263d82d1168f3bd,
title = "Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration",
abstract = "Manaevite-(Ce), a new vesuvianite-group mineral has been investigated by means of electron microprobe, TGA and DSC and CHN analysis of H2O, powder X-ray diffraction, single-crystal X-ray structure analysis, 139La NMR, 57Fe M{\"o}ssbauer spectroscopy, IR spectroscopy and optical measurements. Tetragonal unit-cell parameters are a = 15.9247(13) {\AA}, c = 11.9661(10) {\AA}, space group P4/nnc. The structure model was solved and refined to R1 = 3.35% for 1757 independent observed reflections with I > 4σ(I). Manaevite-(Ce) is the first vesuvianite-group mineral with the species-defining role of REE3+ at the X3 site. The mineral contains two different kinds of hydroxyl anions. The first type of hydroxyl groups is associated with the O10 and O11 sites as observed for other vesuvianite-group members. Another type of OH groups is due to the hydrogarnet substitution (H4O4)4‒ ↔ (SiO4) 4‒ associated with the Z1 and Z2 sites. The incorporation of REE3+ into the crystal structure of manaevite-(Ce) proceeds via the substitution schemes 2Ca2+ ↔ Th4+ + □ and 3Ca2+ ↔ 2REE3+ + □, which results in the formation of vacancies at the X3 site and the presence of H2O molecules.",
keywords = "La NMR spectroscopy, Crystal chemistry, Manaevite-(ce), M{\"o}ssbauer spectroscopy, New mineral, REE, Vesuvianite",
author = "Moiseev, {Mikhail M.} and Panikorovskii, {Taras L.} and Aksenov, {Sergey M.} and Mazur, {Anton S.} and Mikhailova, {Julia A.} and Yakovenchuk, {Victor N.} and Bazai, {Ayya V.} and Ivanyuk, {Gregory Yu} and Agakhanov, {Atali A.} and Shilovskikh, {Vladimir V.} and Pekov, {Igor V.} and Kasatkin, {Anatoly V.} and Rusakov, {Vyacheslav S.} and Yapaskurt, {Vasiliy O.} and Karpenko, {Vladimir Yu} and Krivovichev, {Sergey V.}",
year = "2020",
month = feb,
day = "22",
doi = "10.1007/s00269-020-01086-7",
language = "English",
volume = "47",
journal = "Physics and Chemistry of Minerals",
issn = "0342-1791",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration

AU - Moiseev, Mikhail M.

AU - Panikorovskii, Taras L.

AU - Aksenov, Sergey M.

AU - Mazur, Anton S.

AU - Mikhailova, Julia A.

AU - Yakovenchuk, Victor N.

AU - Bazai, Ayya V.

AU - Ivanyuk, Gregory Yu

AU - Agakhanov, Atali A.

AU - Shilovskikh, Vladimir V.

AU - Pekov, Igor V.

AU - Kasatkin, Anatoly V.

AU - Rusakov, Vyacheslav S.

AU - Yapaskurt, Vasiliy O.

AU - Karpenko, Vladimir Yu

AU - Krivovichev, Sergey V.

PY - 2020/2/22

Y1 - 2020/2/22

N2 - Manaevite-(Ce), a new vesuvianite-group mineral has been investigated by means of electron microprobe, TGA and DSC and CHN analysis of H2O, powder X-ray diffraction, single-crystal X-ray structure analysis, 139La NMR, 57Fe Mössbauer spectroscopy, IR spectroscopy and optical measurements. Tetragonal unit-cell parameters are a = 15.9247(13) Å, c = 11.9661(10) Å, space group P4/nnc. The structure model was solved and refined to R1 = 3.35% for 1757 independent observed reflections with I > 4σ(I). Manaevite-(Ce) is the first vesuvianite-group mineral with the species-defining role of REE3+ at the X3 site. The mineral contains two different kinds of hydroxyl anions. The first type of hydroxyl groups is associated with the O10 and O11 sites as observed for other vesuvianite-group members. Another type of OH groups is due to the hydrogarnet substitution (H4O4)4‒ ↔ (SiO4) 4‒ associated with the Z1 and Z2 sites. The incorporation of REE3+ into the crystal structure of manaevite-(Ce) proceeds via the substitution schemes 2Ca2+ ↔ Th4+ + □ and 3Ca2+ ↔ 2REE3+ + □, which results in the formation of vacancies at the X3 site and the presence of H2O molecules.

AB - Manaevite-(Ce), a new vesuvianite-group mineral has been investigated by means of electron microprobe, TGA and DSC and CHN analysis of H2O, powder X-ray diffraction, single-crystal X-ray structure analysis, 139La NMR, 57Fe Mössbauer spectroscopy, IR spectroscopy and optical measurements. Tetragonal unit-cell parameters are a = 15.9247(13) Å, c = 11.9661(10) Å, space group P4/nnc. The structure model was solved and refined to R1 = 3.35% for 1757 independent observed reflections with I > 4σ(I). Manaevite-(Ce) is the first vesuvianite-group mineral with the species-defining role of REE3+ at the X3 site. The mineral contains two different kinds of hydroxyl anions. The first type of hydroxyl groups is associated with the O10 and O11 sites as observed for other vesuvianite-group members. Another type of OH groups is due to the hydrogarnet substitution (H4O4)4‒ ↔ (SiO4) 4‒ associated with the Z1 and Z2 sites. The incorporation of REE3+ into the crystal structure of manaevite-(Ce) proceeds via the substitution schemes 2Ca2+ ↔ Th4+ + □ and 3Ca2+ ↔ 2REE3+ + □, which results in the formation of vacancies at the X3 site and the presence of H2O molecules.

KW - La NMR spectroscopy

KW - Crystal chemistry

KW - Manaevite-(ce)

KW - Mössbauer spectroscopy

KW - New mineral

KW - REE

KW - Vesuvianite

UR - http://www.scopus.com/inward/record.url?scp=85081064225&partnerID=8YFLogxK

U2 - 10.1007/s00269-020-01086-7

DO - 10.1007/s00269-020-01086-7

M3 - Article

AN - SCOPUS:85081064225

VL - 47

JO - Physics and Chemistry of Minerals

JF - Physics and Chemistry of Minerals

SN - 0342-1791

IS - 3

M1 - 18

ER -

ID: 62881392