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Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles. / Seidl, Michael; Weinzierl, Rudolf; Timoshkin, Alexey Y.; Scheer, Manfred.

In: Chemistry - A European Journal, Vol. 22, No. 16, 11.04.2016, p. 5484-5488.

Research output: Contribution to journal › Article › peer-review

Harvard

Seidl, M, Weinzierl, R, Timoshkin, AY & Scheer, M 2016, 'Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles', Chemistry - A European Journal, vol. 22, no. 16, pp. 5484-5488. https://doi.org/10.1002/chem.201504954

APA

Seidl, M., Weinzierl, R., Timoshkin, A. Y., & Scheer, M. (2016). Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles. Chemistry - A European Journal, 22(16), 5484-5488. https://doi.org/10.1002/chem.201504954

Vancouver

Seidl M, Weinzierl R, Timoshkin AY, Scheer M. Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles. Chemistry - A European Journal. 2016 Apr 11;22(16):5484-5488. https://doi.org/10.1002/chem.201504954

Author

Seidl, Michael ; Weinzierl, Rudolf ; Timoshkin, Alexey Y. ; Scheer, Manfred. / Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles. In: Chemistry - A European Journal. 2016 ; Vol. 22, No. 16. pp. 5484-5488.

BibTeX

@article{1e50cf035e0348d8819e9ab101fe7ab0,
title = "Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles",
abstract = "The phosphinidene complex [Cp∗P{W(CO)5}2] (1; Cp∗=C5Me5) reacted with malononitrile to give the 1,2-dihydro-1,3,2-diazaphosphinine derivative 2. The reaction of 1 with 1,4-benzodinitrile gave [1,4-{{W(CO)5}2P-N=C(Cp∗)}2(C6H4)] (3), the first example of a cumulene-like aminophosphinidene complex. The reaction of 1 with aniline gave the aminophosphinidene complex [(Ph)N(H)P{W(CO)5}2] (4). To compare the reactivity of benzonitrile and aniline with 1, the phosphinidene complex 1 was reacted with three different isomers of aminobenzonitrile (2-, 3-, and 4-aminobenzonitrile). These reactions gave an insight into the reaction pathway of 1 with benzonitrile derivatives. Compounds 5, 6 a, 6 b, and 7, which are derivatives of 1,2-dihydro-1,3,2-diazaphosphinine or benzo-2H-1,2-azaphospholes, were, as well as all other products, characterized by mass spectrometry, NMR and IR spectroscopy, and X-ray structure analysis.",
keywords = "heterocycles, nitriles, phosphinidenes, phosphorus",
author = "Michael Seidl and Rudolf Weinzierl and Timoshkin, {Alexey Y.} and Manfred Scheer",
year = "2016",
month = apr,
day = "11",
doi = "10.1002/chem.201504954",
language = "English",
volume = "22",
pages = "5484--5488",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "16",

}

RIS

TY - JOUR

T1 - Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles

AU - Seidl, Michael

AU - Weinzierl, Rudolf

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

PY - 2016/4/11

Y1 - 2016/4/11

N2 - The phosphinidene complex [Cp∗P{W(CO)5}2] (1; Cp∗=C5Me5) reacted with malononitrile to give the 1,2-dihydro-1,3,2-diazaphosphinine derivative 2. The reaction of 1 with 1,4-benzodinitrile gave [1,4-{{W(CO)5}2P-N=C(Cp∗)}2(C6H4)] (3), the first example of a cumulene-like aminophosphinidene complex. The reaction of 1 with aniline gave the aminophosphinidene complex [(Ph)N(H)P{W(CO)5}2] (4). To compare the reactivity of benzonitrile and aniline with 1, the phosphinidene complex 1 was reacted with three different isomers of aminobenzonitrile (2-, 3-, and 4-aminobenzonitrile). These reactions gave an insight into the reaction pathway of 1 with benzonitrile derivatives. Compounds 5, 6 a, 6 b, and 7, which are derivatives of 1,2-dihydro-1,3,2-diazaphosphinine or benzo-2H-1,2-azaphospholes, were, as well as all other products, characterized by mass spectrometry, NMR and IR spectroscopy, and X-ray structure analysis.

AB - The phosphinidene complex [Cp∗P{W(CO)5}2] (1; Cp∗=C5Me5) reacted with malononitrile to give the 1,2-dihydro-1,3,2-diazaphosphinine derivative 2. The reaction of 1 with 1,4-benzodinitrile gave [1,4-{{W(CO)5}2P-N=C(Cp∗)}2(C6H4)] (3), the first example of a cumulene-like aminophosphinidene complex. The reaction of 1 with aniline gave the aminophosphinidene complex [(Ph)N(H)P{W(CO)5}2] (4). To compare the reactivity of benzonitrile and aniline with 1, the phosphinidene complex 1 was reacted with three different isomers of aminobenzonitrile (2-, 3-, and 4-aminobenzonitrile). These reactions gave an insight into the reaction pathway of 1 with benzonitrile derivatives. Compounds 5, 6 a, 6 b, and 7, which are derivatives of 1,2-dihydro-1,3,2-diazaphosphinine or benzo-2H-1,2-azaphospholes, were, as well as all other products, characterized by mass spectrometry, NMR and IR spectroscopy, and X-ray structure analysis.

KW - heterocycles

KW - nitriles

KW - phosphinidenes

KW - phosphorus

UR - http://www.scopus.com/inward/record.url?scp=84960153670&partnerID=8YFLogxK

U2 - 10.1002/chem.201504954

DO - 10.1002/chem.201504954

M3 - Article

VL - 22

SP - 5484

EP - 5488

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 16

ER -

ID: 7560822