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Influence of carbonate ion in the crystallization medium on the formation and chemical composition of CaHA–SrHA solid solutions. / Nikolaev, A.; Kuz'mina, M.; Frank-Kamenetskaya, O.; Zorina, M.

In: Journal of Molecular Structure, No. 1089, 2015, p. 73-80.

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@article{91caa7679dda479a9359346f43a81ee2,
title = "Influence of carbonate ion in the crystallization medium on the formation and chemical composition of CaHA–SrHA solid solutions",
abstract = "The study of the influence of carbonate ions in a solution to Sr-distribution in system «solution–crystal» andto ion substitutionsand the non-stoichiometry offormed CaHA–SrHA solid solutions was carried out. The CaHA–SrHA solid solutions were synthesized by precipitation from aqueous solutions with the atomic C/P ratio equal to 0, 0.05 and 0.1 at T = 90C. Resulting precipitates were studied using various methods including X-ray powder diffraction, infrared spectroscopy and different chemical analyses. The results of the study have shown that in the range of values of (Ca + Sr)/P in the water solution from 40% to 85%, the presence of carbonate ions (C/P = 0.05–0.1) promotes the incorporation of strontium in the apatite. Crystalline apatite solid solutions formed from water solutions of such composition are more defective compared to apatites that are mainly calcium or strontium. They are characterized by a smaller size coherence scattering domain length along [001] direction and a greater number of carbonate io",
keywords = "Carbonated strontium hydroxyapatite, Synthesis, Crystallization, Precipitation method, Powder X-ray diffraction, Infrared spectroscopy",
author = "A. Nikolaev and M. Kuz'mina and O. Frank-Kamenetskaya and M. Zorina",
year = "2015",
doi = "10.1016/j.molstruc.2015.02.018",
language = "English",
pages = "73--80",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",
number = "1089",

}

RIS

TY - JOUR

T1 - Influence of carbonate ion in the crystallization medium on the formation and chemical composition of CaHA–SrHA solid solutions

AU - Nikolaev, A.

AU - Kuz'mina, M.

AU - Frank-Kamenetskaya, O.

AU - Zorina, M.

PY - 2015

Y1 - 2015

N2 - The study of the influence of carbonate ions in a solution to Sr-distribution in system «solution–crystal» andto ion substitutionsand the non-stoichiometry offormed CaHA–SrHA solid solutions was carried out. The CaHA–SrHA solid solutions were synthesized by precipitation from aqueous solutions with the atomic C/P ratio equal to 0, 0.05 and 0.1 at T = 90C. Resulting precipitates were studied using various methods including X-ray powder diffraction, infrared spectroscopy and different chemical analyses. The results of the study have shown that in the range of values of (Ca + Sr)/P in the water solution from 40% to 85%, the presence of carbonate ions (C/P = 0.05–0.1) promotes the incorporation of strontium in the apatite. Crystalline apatite solid solutions formed from water solutions of such composition are more defective compared to apatites that are mainly calcium or strontium. They are characterized by a smaller size coherence scattering domain length along [001] direction and a greater number of carbonate io

AB - The study of the influence of carbonate ions in a solution to Sr-distribution in system «solution–crystal» andto ion substitutionsand the non-stoichiometry offormed CaHA–SrHA solid solutions was carried out. The CaHA–SrHA solid solutions were synthesized by precipitation from aqueous solutions with the atomic C/P ratio equal to 0, 0.05 and 0.1 at T = 90C. Resulting precipitates were studied using various methods including X-ray powder diffraction, infrared spectroscopy and different chemical analyses. The results of the study have shown that in the range of values of (Ca + Sr)/P in the water solution from 40% to 85%, the presence of carbonate ions (C/P = 0.05–0.1) promotes the incorporation of strontium in the apatite. Crystalline apatite solid solutions formed from water solutions of such composition are more defective compared to apatites that are mainly calcium or strontium. They are characterized by a smaller size coherence scattering domain length along [001] direction and a greater number of carbonate io

KW - Carbonated strontium hydroxyapatite

KW - Synthesis

KW - Crystallization

KW - Precipitation method

KW - Powder X-ray diffraction

KW - Infrared spectroscopy

U2 - 10.1016/j.molstruc.2015.02.018

DO - 10.1016/j.molstruc.2015.02.018

M3 - Article

SP - 73

EP - 80

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

IS - 1089

ER -

ID: 3929080