Increasing the Plasticity of Chalcogenide Glasses in the System Ag2Se-Sb2Se3-GeSe2

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Increasing the Plasticity of Chalcogenide Glasses in the System Ag₂Se-Sb₂Se₃-GeSe₂. / Tveryanovich, Yury S.; Fazletdinov, Timur R.; Tverjanovich, Andrey S.; Pankin, Dmitrii V.; Smirnov, Egor V.; Tolochko, Oleg V.; Panov, Maxim S.; Churbanov, Mikhail F.; Skripachev, Igor V.; Shevelko, Mikhail M.

In: Chemistry of Materials, Vol. 34, No. 6, 22.03.2022, p. 2743-2751.

Research output: Contribution to journal › Article › peer-review

Author

Tveryanovich, Yury S. ; Fazletdinov, Timur R. ; Tverjanovich, Andrey S. ; Pankin, Dmitrii V. ; Smirnov, Egor V. ; Tolochko, Oleg V. ; Panov, Maxim S. ; Churbanov, Mikhail F. ; Skripachev, Igor V. ; Shevelko, Mikhail M. / Increasing the Plasticity of Chalcogenide Glasses in the System Ag₂Se-Sb₂Se₃-GeSe₂. In: Chemistry of Materials. 2022 ; Vol. 34, No. 6. pp. 2743-2751.

BibTeX

@article{9e42e11bb9594f23bf769003099b96cc,

title = "Increasing the Plasticity of Chalcogenide Glasses in the System Ag2Se-Sb2Se3-GeSe2",

abstract = "We proposed a new concept of increasing the plasticity of chalcogenide glasses while maintaining a high glass transition temperature. The main idea of this concept lies in the formation of Ag-Ag metallophilic interactions when silver chalcogenide is introduced into the glass composition. This suggestion was confirmed by the experimental study of glasses based on the Ag2Se-Sb2Se3-GeSe2system. It was observed that the introduction of 40 mole percent of Ag2Se into the glass composition leads to the increase of its plasticity by 3.5 times, whereas the glass transition temperature of such glass remains higher than 200 °C. The most typical application area of these materials is infrared (IR) optics. In our case, the addition of silver not only improves the mechanical properties of a glass but also allows one to keep the position of the fundamental absorption edge in the near-IR region (900 nm), which is quite suitable for the aforementioned applications.",

author = "Tveryanovich, {Yury S.} and Fazletdinov, {Timur R.} and Tverjanovich, {Andrey S.} and Pankin, {Dmitrii V.} and Smirnov, {Egor V.} and Tolochko, {Oleg V.} and Panov, {Maxim S.} and Churbanov, {Mikhail F.} and Skripachev, {Igor V.} and Shevelko, {Mikhail M.}",

year = "2022",

month = mar,

day = "22",

doi = "10.1021/acs.chemmater.1c04312",

language = "English",

volume = "34",

pages = "2743--2751",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "6",

}

RIS

TY - JOUR

T1 - Increasing the Plasticity of Chalcogenide Glasses in the System Ag2Se-Sb2Se3-GeSe2

AU - Tveryanovich, Yury S.

AU - Fazletdinov, Timur R.

AU - Tverjanovich, Andrey S.

AU - Pankin, Dmitrii V.

AU - Smirnov, Egor V.

AU - Tolochko, Oleg V.

AU - Panov, Maxim S.

AU - Churbanov, Mikhail F.

AU - Skripachev, Igor V.

AU - Shevelko, Mikhail M.

PY - 2022/3/22

Y1 - 2022/3/22

N2 - We proposed a new concept of increasing the plasticity of chalcogenide glasses while maintaining a high glass transition temperature. The main idea of this concept lies in the formation of Ag-Ag metallophilic interactions when silver chalcogenide is introduced into the glass composition. This suggestion was confirmed by the experimental study of glasses based on the Ag2Se-Sb2Se3-GeSe2system. It was observed that the introduction of 40 mole percent of Ag2Se into the glass composition leads to the increase of its plasticity by 3.5 times, whereas the glass transition temperature of such glass remains higher than 200 °C. The most typical application area of these materials is infrared (IR) optics. In our case, the addition of silver not only improves the mechanical properties of a glass but also allows one to keep the position of the fundamental absorption edge in the near-IR region (900 nm), which is quite suitable for the aforementioned applications.

AB - We proposed a new concept of increasing the plasticity of chalcogenide glasses while maintaining a high glass transition temperature. The main idea of this concept lies in the formation of Ag-Ag metallophilic interactions when silver chalcogenide is introduced into the glass composition. This suggestion was confirmed by the experimental study of glasses based on the Ag2Se-Sb2Se3-GeSe2system. It was observed that the introduction of 40 mole percent of Ag2Se into the glass composition leads to the increase of its plasticity by 3.5 times, whereas the glass transition temperature of such glass remains higher than 200 °C. The most typical application area of these materials is infrared (IR) optics. In our case, the addition of silver not only improves the mechanical properties of a glass but also allows one to keep the position of the fundamental absorption edge in the near-IR region (900 nm), which is quite suitable for the aforementioned applications.

UR - http://www.scopus.com/inward/record.url?scp=85126125461&partnerID=8YFLogxK

U2 - 10.1021/acs.chemmater.1c04312

DO - 10.1021/acs.chemmater.1c04312

M3 - Article

AN - SCOPUS:85126125461

VL - 34

SP - 2743

EP - 2751

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 6

ER -

ID: 96790814