Standard

Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions. / Volkov, S.; Bubnova, R.; Bolotina, N.; Krzhizhanovskaya, M.; Belousova, O.; Filatov, S.

In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 71, 2015, p. 489-497.

Research output: Contribution to journal › Article › peer-review

Harvard

Volkov, S, Bubnova, R, Bolotina, N, Krzhizhanovskaya, M, Belousova, O & Filatov, S 2015, 'Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions', Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, vol. 71, pp. 489-497. https://doi.org/10.1107/S2052520615011713

APA

Volkov, S., Bubnova, R., Bolotina, N., Krzhizhanovskaya, M., Belousova, O., & Filatov, S. (2015). Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 71, 489-497. https://doi.org/10.1107/S2052520615011713

Vancouver

Volkov S, Bubnova R, Bolotina N, Krzhizhanovskaya M, Belousova O, Filatov S. Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2015;71:489-497. https://doi.org/10.1107/S2052520615011713

Author

Volkov, S. ; Bubnova, R. ; Bolotina, N. ; Krzhizhanovskaya, M. ; Belousova, O. ; Filatov, S. / Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions. In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2015 ; Vol. 71. pp. 489-497.

BibTeX

@article{e2bbf4fcbc314280b0c47d2b350ffc67,
title = "Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions",
abstract = "Crystal structures of Sr3B2 (+) Si-x(1) (-) O-x(8) (- x/2) solid solutions with nominal compositions x = 0.28, 0.53, 0.78 in the Sr3B2SiO8-Sr2B2O5 section of the SrO-B2O3-SiO2 system are refined using single-crystal X-ray diffraction data. Incommensurate structure modulations are mainly associated with various orientations of corner-sharing (B,Si)-polyhedra. Preference is given to the (3 + 2)-dimensional symmetry group Pnma(0 beta gamma)000(0 beta gamma)000 for a single crystal compared with an alternate model of a twin formed by monoclinic components, each of them corresponding to the (3 + 1)-dimensional symmetry group P2(1)/n(0 beta gamma). Single-phase polycrystalline samples of solid solutions are investigated by high-temperature X-ray powder diffraction in air. Orientation preferences of the BO3 units lead to a strong anisotropy of thermal expansion. Negative expansion is observed along the a axis over the temperature range 303-753 K. Anisotropy decreases both on heating and decreasing of the boron conte",
author = "S. Volkov and R. Bubnova and N. Bolotina and M. Krzhizhanovskaya and O. Belousova and S. Filatov",
year = "2015",
doi = "10.1107/S2052520615011713",
language = "English",
volume = "71",
pages = "489--497",
journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials",
issn = "2052-5192",
publisher = "International Union of Crystallography",

}

RIS

TY - JOUR

T1 - Incommensurate modulation and thermal expansion of Sr3B2 (+) Si-x(1) (-) O-x(8) (-) (x/2) solid solutions

AU - Volkov, S.

AU - Bubnova, R.

AU - Bolotina, N.

AU - Krzhizhanovskaya, M.

AU - Belousova, O.

AU - Filatov, S.

PY - 2015

Y1 - 2015

N2 - Crystal structures of Sr3B2 (+) Si-x(1) (-) O-x(8) (- x/2) solid solutions with nominal compositions x = 0.28, 0.53, 0.78 in the Sr3B2SiO8-Sr2B2O5 section of the SrO-B2O3-SiO2 system are refined using single-crystal X-ray diffraction data. Incommensurate structure modulations are mainly associated with various orientations of corner-sharing (B,Si)-polyhedra. Preference is given to the (3 + 2)-dimensional symmetry group Pnma(0 beta gamma)000(0 beta gamma)000 for a single crystal compared with an alternate model of a twin formed by monoclinic components, each of them corresponding to the (3 + 1)-dimensional symmetry group P2(1)/n(0 beta gamma). Single-phase polycrystalline samples of solid solutions are investigated by high-temperature X-ray powder diffraction in air. Orientation preferences of the BO3 units lead to a strong anisotropy of thermal expansion. Negative expansion is observed along the a axis over the temperature range 303-753 K. Anisotropy decreases both on heating and decreasing of the boron conte

AB - Crystal structures of Sr3B2 (+) Si-x(1) (-) O-x(8) (- x/2) solid solutions with nominal compositions x = 0.28, 0.53, 0.78 in the Sr3B2SiO8-Sr2B2O5 section of the SrO-B2O3-SiO2 system are refined using single-crystal X-ray diffraction data. Incommensurate structure modulations are mainly associated with various orientations of corner-sharing (B,Si)-polyhedra. Preference is given to the (3 + 2)-dimensional symmetry group Pnma(0 beta gamma)000(0 beta gamma)000 for a single crystal compared with an alternate model of a twin formed by monoclinic components, each of them corresponding to the (3 + 1)-dimensional symmetry group P2(1)/n(0 beta gamma). Single-phase polycrystalline samples of solid solutions are investigated by high-temperature X-ray powder diffraction in air. Orientation preferences of the BO3 units lead to a strong anisotropy of thermal expansion. Negative expansion is observed along the a axis over the temperature range 303-753 K. Anisotropy decreases both on heating and decreasing of the boron conte

U2 - 10.1107/S2052520615011713

DO - 10.1107/S2052520615011713

M3 - Article

VL - 71

SP - 489

EP - 497

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

SN - 2052-5192

ER -

ID: 4000819