• D. A. Andronikova
  • Iu A. Bronwald
  • I. N. Leontiev
  • N. G. Leontiev
  • D. Yu Chernyshov
  • A. V. Filimonov
  • S. B. Vakhrushev

Detailed study of the X-ray diffuse scattering in the paraelectric phase of the PbZr0.985Ti0.015O3 was carried out. We concentrated on the analysis of the scattering peculiarities in the vicinities of M- and R- points of the Brillouin zone. We have observed a critical increase of the diffuse scattering at the position Q ≈ (0.47 + h 0.53 + k l) slightly aside of M point on cooling to the intermediate phase. We attribute observed critical scattering to a mixed mode containing both oxygen octahedral tilts and antiparallel cationic displacements. Tentative conclusion is made describing earlier reported complicated set of the satellite peaks around M-point as the result of the soft-mode driven incommensurate phase transition.

Original languageEnglish
Pages (from-to)65-73
Number of pages9
JournalFerroelectrics
Volume538
Issue number1
DOIs
StatePublished - 2 Jan 2019

    Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

    Research areas

  • diffuse scattering, Ferroelectricity, phase transitions

ID: 97788493