Research output: Contribution to journal › Article › peer-review
In situmicrosynthesis of polyaniline : synthesis-structure-conductivity correlation. / Vasileva, Anna; Pankin, Dmitrii; Mikhailovskii, Vladimir; Kolesnikov, Ilya; Mínguez-Bacho, Ignacio; Bachmann, Julien; Manshina, Alina.
In: New Journal of Chemistry, Vol. 45, No. 35, 21.09.2021, p. 15968-15976.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - In situmicrosynthesis of polyaniline
T2 - synthesis-structure-conductivity correlation
AU - Vasileva, Anna
AU - Pankin, Dmitrii
AU - Mikhailovskii, Vladimir
AU - Kolesnikov, Ilya
AU - Mínguez-Bacho, Ignacio
AU - Bachmann, Julien
AU - Manshina, Alina
N1 - Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.
PY - 2021/9/21
Y1 - 2021/9/21
N2 - Anin situmicrosynthesis of polyaniline films directly on a substrate was developed and considered from the viewpoint of conductivity as a key functional property. The microsynthesis was carried out in a reaction volume of 60 μL. The multi-analytical study of polyaniline samples obtained byin situmicrosynthesis was performed. The effect of synthesis parameters (reaction time, temperature, and number of synthetic procedures on the same substrate) on the structure, morphology and conductivity was investigated. It was shown that thein situmicrosynthesis allows for the formation of polyaniline films in the whole range of synthesis parameters chosen. The correlations between synthetic conditions, structural parameters and conductivity are discussed. The found correlations between FTIR parameters and conductivity can be considered as a promising tool for PANI characterization.
AB - Anin situmicrosynthesis of polyaniline films directly on a substrate was developed and considered from the viewpoint of conductivity as a key functional property. The microsynthesis was carried out in a reaction volume of 60 μL. The multi-analytical study of polyaniline samples obtained byin situmicrosynthesis was performed. The effect of synthesis parameters (reaction time, temperature, and number of synthetic procedures on the same substrate) on the structure, morphology and conductivity was investigated. It was shown that thein situmicrosynthesis allows for the formation of polyaniline films in the whole range of synthesis parameters chosen. The correlations between synthetic conditions, structural parameters and conductivity are discussed. The found correlations between FTIR parameters and conductivity can be considered as a promising tool for PANI characterization.
KW - ANILINE DERIVATIVES
KW - POLYMERIZATION
KW - EMERALDINE
KW - NANOSTRUCTURES
KW - DEPOSITION
KW - OLIGOMERS
KW - ELECTRODE
KW - POLYMERS
KW - SALT
KW - FILM
UR - http://www.scopus.com/inward/record.url?scp=85115061351&partnerID=8YFLogxK
U2 - 10.1039/d1nj03198h
DO - 10.1039/d1nj03198h
M3 - Article
AN - SCOPUS:85115061351
VL - 45
SP - 15968
EP - 15976
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 35
ER -
ID: 85980616