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Imidometallanes and their heavy analogs : Rich gas phase chemistry of ring and cluster compounds. / Timoshkin, Alexey Y.

In: Inorganic Chemistry Communications, Vol. 6, No. 3, 01.03.2003, p. 274-277.

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Timoshkin, Alexey Y. / Imidometallanes and their heavy analogs : Rich gas phase chemistry of ring and cluster compounds. In: Inorganic Chemistry Communications. 2003 ; Vol. 6, No. 3. pp. 274-277.

BibTeX

@article{4b7d48927e1a419ab28bde03f33b3d7f,
title = "Imidometallanes and their heavy analogs: Rich gas phase chemistry of ring and cluster compounds",
abstract = "Thermodynamic properties of the group 13-15 pnictidometallanes [HMYH]n, (M = Al, Ga, In; Y = N, P, As; n = 1-16) have been predicted at the B3LYP/LANL2DZ(d,p) level of theory. Process of the gas phase generation of [HMYH]n clusters is favorable thermodynamically at low temperatures. Al and N-containing clusters are predicted to be exceptionally stable. Spontaneous generation of [RMYH]n oligomers with n = 12-14 is expected during chemical vapor deposition processes at low temperature-high pressure conditions.",
keywords = "13-15 coordination compounds, Clusters, Quantum chemistry, Thermodynamics",
author = "Timoshkin, {Alexey Y.}",
year = "2003",
month = mar,
day = "1",
doi = "10.1016/S1387-7003(02)00745-1",
language = "English",
volume = "6",
pages = "274--277",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",
number = "3",

}

RIS

TY - JOUR

T1 - Imidometallanes and their heavy analogs

T2 - Rich gas phase chemistry of ring and cluster compounds

AU - Timoshkin, Alexey Y.

PY - 2003/3/1

Y1 - 2003/3/1

N2 - Thermodynamic properties of the group 13-15 pnictidometallanes [HMYH]n, (M = Al, Ga, In; Y = N, P, As; n = 1-16) have been predicted at the B3LYP/LANL2DZ(d,p) level of theory. Process of the gas phase generation of [HMYH]n clusters is favorable thermodynamically at low temperatures. Al and N-containing clusters are predicted to be exceptionally stable. Spontaneous generation of [RMYH]n oligomers with n = 12-14 is expected during chemical vapor deposition processes at low temperature-high pressure conditions.

AB - Thermodynamic properties of the group 13-15 pnictidometallanes [HMYH]n, (M = Al, Ga, In; Y = N, P, As; n = 1-16) have been predicted at the B3LYP/LANL2DZ(d,p) level of theory. Process of the gas phase generation of [HMYH]n clusters is favorable thermodynamically at low temperatures. Al and N-containing clusters are predicted to be exceptionally stable. Spontaneous generation of [RMYH]n oligomers with n = 12-14 is expected during chemical vapor deposition processes at low temperature-high pressure conditions.

KW - 13-15 coordination compounds

KW - Clusters

KW - Quantum chemistry

KW - Thermodynamics

UR - http://www.scopus.com/inward/record.url?scp=0037362527&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(02)00745-1

DO - 10.1016/S1387-7003(02)00745-1

M3 - Article

AN - SCOPUS:0037362527

VL - 6

SP - 274

EP - 277

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 3

ER -

ID: 17373559