Research output: Contribution to journal › Article › peer-review
Identification of the Structure of Polybutadiene Terminal Units by NMR Spectroscopy with T 2-Filter. / Rozentsvet, V. A.; Sablina, N. A.; Ulyanova, D. M.; Tolstoy, P. M.; Smirnov, S. N.; Novakov, I. A.
In: Doklady Physical Chemistry, Vol. 491, No. 2, 01.04.2020, p. 40-42.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Identification of the Structure of Polybutadiene Terminal Units by NMR Spectroscopy with T 2-Filter
AU - Rozentsvet, V. A.
AU - Sablina, N. A.
AU - Ulyanova, D. M.
AU - Tolstoy, P. M.
AU - Smirnov, S. N.
AU - Novakov, I. A.
PY - 2020/4/1
Y1 - 2020/4/1
N2 - Abstract: A new method for the identification of the structure of terminal units in polybutadiene synthesized by cationic polymerization has been developed. The method consists of conducting T2-filtered NMR experiments, which make it possible to reduce the intensities of the spectral signals of the main-chain carbon atoms and significantly increase the intensities of the signals of the carbon atoms in the head and end polybutadiene units characterized by higher mobility.
AB - Abstract: A new method for the identification of the structure of terminal units in polybutadiene synthesized by cationic polymerization has been developed. The method consists of conducting T2-filtered NMR experiments, which make it possible to reduce the intensities of the spectral signals of the main-chain carbon atoms and significantly increase the intensities of the signals of the carbon atoms in the head and end polybutadiene units characterized by higher mobility.
KW - NMR
KW - polybutadiene
KW - structure of terminal units
KW - T-filter
KW - T-2-filter
UR - http://www.scopus.com/inward/record.url?scp=85088260086&partnerID=8YFLogxK
U2 - 10.1134/S0012501620040028
DO - 10.1134/S0012501620040028
M3 - Article
AN - SCOPUS:85088260086
VL - 491
SP - 40
EP - 42
JO - Doklady Physical Chemistry
JF - Doklady Physical Chemistry
SN - 0012-5016
IS - 2
ER -
ID: 61522458