Standard

Hyperfine structure constants for diatomic molecules. / Tupitsyn, I.; Kotochigova, S.

In: Journal of Research of the National Institute of Standards and Technology, Vol. 103, No. 2, 01.01.1998, p. 205-207.

Research output: Contribution to journal › Article › peer-review

Harvard

Tupitsyn, I & Kotochigova, S 1998, 'Hyperfine structure constants for diatomic molecules', Journal of Research of the National Institute of Standards and Technology, vol. 103, no. 2, pp. 205-207. https://doi.org/10.6028/jres.103.014

APA

Tupitsyn, I., & Kotochigova, S. (1998). Hyperfine structure constants for diatomic molecules. Journal of Research of the National Institute of Standards and Technology, 103(2), 205-207. https://doi.org/10.6028/jres.103.014

Vancouver

Tupitsyn I, Kotochigova S. Hyperfine structure constants for diatomic molecules. Journal of Research of the National Institute of Standards and Technology. 1998 Jan 1;103(2):205-207. https://doi.org/10.6028/jres.103.014

Author

Tupitsyn, I. ; Kotochigova, S. / Hyperfine structure constants for diatomic molecules. In: Journal of Research of the National Institute of Standards and Technology. 1998 ; Vol. 103, No. 2. pp. 205-207.

BibTeX

@article{5969fbd61fb74dd9812ffb21e243e0e2,
title = "Hyperfine structure constants for diatomic molecules",
abstract = "The multiconfiguration valence-bond method (VB) is applied to diatomic molecules using the Hartree-Fock (HF) atomic basis set. The hyperfine constant, Fermi contact term, is computed as a function of the interatomic separation for the X2Πground state of 17OH and X1Σ ground state of 107AgH+ molecules. This study leads to a number of conclusions about the influence of correlation and polarization effects on the hyperfine structure of hydrogenic molecules. The calculated values of the Fermi contact term are found to agree within 1 % of the experimental values wherever available.",
keywords = "Diatomic molecules, Fermi contact term, Hyperfine structure, OH molecule, Valence-bond method",
author = "I. Tupitsyn and S. Kotochigova",
year = "1998",
month = jan,
day = "1",
doi = "10.6028/jres.103.014",
language = "English",
volume = "103",
pages = "205--207",
journal = "J Res Nat Bur Stand Sec A Phys Chem",
issn = "1044-677X",
publisher = "National Institute of Standards and Technology",
number = "2",

}

RIS

TY - JOUR

T1 - Hyperfine structure constants for diatomic molecules

AU - Tupitsyn, I.

AU - Kotochigova, S.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - The multiconfiguration valence-bond method (VB) is applied to diatomic molecules using the Hartree-Fock (HF) atomic basis set. The hyperfine constant, Fermi contact term, is computed as a function of the interatomic separation for the X2Πground state of 17OH and X1Σ ground state of 107AgH+ molecules. This study leads to a number of conclusions about the influence of correlation and polarization effects on the hyperfine structure of hydrogenic molecules. The calculated values of the Fermi contact term are found to agree within 1 % of the experimental values wherever available.

AB - The multiconfiguration valence-bond method (VB) is applied to diatomic molecules using the Hartree-Fock (HF) atomic basis set. The hyperfine constant, Fermi contact term, is computed as a function of the interatomic separation for the X2Πground state of 17OH and X1Σ ground state of 107AgH+ molecules. This study leads to a number of conclusions about the influence of correlation and polarization effects on the hyperfine structure of hydrogenic molecules. The calculated values of the Fermi contact term are found to agree within 1 % of the experimental values wherever available.

KW - Diatomic molecules

KW - Fermi contact term

KW - Hyperfine structure

KW - OH molecule

KW - Valence-bond method

UR - http://www.scopus.com/inward/record.url?scp=0032022964&partnerID=8YFLogxK

U2 - 10.6028/jres.103.014

DO - 10.6028/jres.103.014

M3 - Article

AN - SCOPUS:0032022964

VL - 103

SP - 205

EP - 207

JO - J Res Nat Bur Stand Sec A Phys Chem

JF - J Res Nat Bur Stand Sec A Phys Chem

SN - 1044-677X

IS - 2

ER -

ID: 49763752