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Hydrolysis of Hexacarbonyltechnetium(I) Cation : Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14. / Miroslavov, Alexander E.; Shishkina, Anna P.; Sidorenko, Georgy V.; Gurzhiy, Vladislav V.; Maltsev, Daniil A.; Kurysheva, Ekaterina V.

In: Inorganic Chemistry, Vol. 59, No. 13, 06.07.2020, p. 9239-9243.

Research output: Contribution to journal › Article › peer-review

Harvard

Miroslavov, AE, Shishkina, AP, Sidorenko, GV, Gurzhiy, VV, Maltsev, DA & Kurysheva, EV 2020, 'Hydrolysis of Hexacarbonyltechnetium(I) Cation: Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14', Inorganic Chemistry, vol. 59, no. 13, pp. 9239-9243. https://doi.org/10.1021/acs.inorgchem.0c01145

APA

Miroslavov, A. E., Shishkina, A. P., Sidorenko, G. V., Gurzhiy, V. V., Maltsev, D. A., & Kurysheva, E. V. (2020). Hydrolysis of Hexacarbonyltechnetium(I) Cation: Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14. Inorganic Chemistry, 59(13), 9239-9243. https://doi.org/10.1021/acs.inorgchem.0c01145

Vancouver

Miroslavov AE, Shishkina AP, Sidorenko GV, Gurzhiy VV, Maltsev DA, Kurysheva EV. Hydrolysis of Hexacarbonyltechnetium(I) Cation: Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14. Inorganic Chemistry. 2020 Jul 6;59(13):9239-9243. https://doi.org/10.1021/acs.inorgchem.0c01145

Author

Miroslavov, Alexander E. ; Shishkina, Anna P. ; Sidorenko, Georgy V. ; Gurzhiy, Vladislav V. ; Maltsev, Daniil A. ; Kurysheva, Ekaterina V. / Hydrolysis of Hexacarbonyltechnetium(I) Cation : Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14. In: Inorganic Chemistry. 2020 ; Vol. 59, No. 13. pp. 9239-9243.

BibTeX

@article{a01b3da8a4564d088a3d52429c984779,
title = "Hydrolysis of Hexacarbonyltechnetium(I) Cation: Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14",
abstract = "Reaction of [99Tc(CO)6]ClO4 with alkali in aqueous solutions yields yellow 99Tc3H(CO)14 as the major product. On the other hand, [99TcH(CO)5] becomes the major product when the reaction with alkali is combined with the extraction into hexane. The molecular structure of 99Tc3H(CO)14, determined by SCXRD, is composed of the 99Tc2(CO)9 fragment bound to the 99Tc(CO)5 fragment via the hydrogen bridge and weak metal-metal bond. This compound crystallizes in the monoclinic system, space group P21/n, a = 9.6954(2) {\AA}, b = 15.0985(3) {\AA}, c = 14.5090(3) {\AA}, and β = 104.925(2)°. 99Tc3H(CO)14 was additionally characterized by IR spectroscopy. The mechanism of hydrolysis of [99Tc(CO)6]ClO4 was suggested.",
author = "Miroslavov, {Alexander E.} and Shishkina, {Anna P.} and Sidorenko, {Georgy V.} and Gurzhiy, {Vladislav V.} and Maltsev, {Daniil A.} and Kurysheva, {Ekaterina V.}",
year = "2020",
month = jul,
day = "6",
doi = "10.1021/acs.inorgchem.0c01145",
language = "English",
volume = "59",
pages = "9239--9243",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Hydrolysis of Hexacarbonyltechnetium(I) Cation

T2 - Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14

AU - Miroslavov, Alexander E.

AU - Shishkina, Anna P.

AU - Sidorenko, Georgy V.

AU - Gurzhiy, Vladislav V.

AU - Maltsev, Daniil A.

AU - Kurysheva, Ekaterina V.

PY - 2020/7/6

Y1 - 2020/7/6

N2 - Reaction of [99Tc(CO)6]ClO4 with alkali in aqueous solutions yields yellow 99Tc3H(CO)14 as the major product. On the other hand, [99TcH(CO)5] becomes the major product when the reaction with alkali is combined with the extraction into hexane. The molecular structure of 99Tc3H(CO)14, determined by SCXRD, is composed of the 99Tc2(CO)9 fragment bound to the 99Tc(CO)5 fragment via the hydrogen bridge and weak metal-metal bond. This compound crystallizes in the monoclinic system, space group P21/n, a = 9.6954(2) Å, b = 15.0985(3) Å, c = 14.5090(3) Å, and β = 104.925(2)°. 99Tc3H(CO)14 was additionally characterized by IR spectroscopy. The mechanism of hydrolysis of [99Tc(CO)6]ClO4 was suggested.

AB - Reaction of [99Tc(CO)6]ClO4 with alkali in aqueous solutions yields yellow 99Tc3H(CO)14 as the major product. On the other hand, [99TcH(CO)5] becomes the major product when the reaction with alkali is combined with the extraction into hexane. The molecular structure of 99Tc3H(CO)14, determined by SCXRD, is composed of the 99Tc2(CO)9 fragment bound to the 99Tc(CO)5 fragment via the hydrogen bridge and weak metal-metal bond. This compound crystallizes in the monoclinic system, space group P21/n, a = 9.6954(2) Å, b = 15.0985(3) Å, c = 14.5090(3) Å, and β = 104.925(2)°. 99Tc3H(CO)14 was additionally characterized by IR spectroscopy. The mechanism of hydrolysis of [99Tc(CO)6]ClO4 was suggested.

UR - http://www.scopus.com/inward/record.url?scp=85087027511&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.0c01145

DO - 10.1021/acs.inorgchem.0c01145

M3 - Article

C2 - 32543190

AN - SCOPUS:85087027511

VL - 59

SP - 9239

EP - 9243

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 13

ER -

ID: 61629905