The stress–strain equation of state for a material with dissolved hydrogen is derived within a twocomponent continuum model. It is demonstrated that, for the parameters corresponding to conventional metals, it has the shape of a loop similar to the van der Waals loop. On this basis, it is concluded that hydrogen embrittlement of materials under load is a typical first-order phase transition and, therefore, occurs through nucleation of a new phase. Thermodynamic and kinetic theories of this transition are developed, and time dependences of all the main characteristics of this process are calculated.

Original languageEnglish
Pages (from-to)1901-1906
Number of pages6
JournalPhysics of the Solid State
Volume51
Issue number9
DOIs
StatePublished - 2009

    Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

ID: 75071899