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The stress–strain equation of state for a material with dissolved hydrogen is derived within a twocomponent continuum model. It is demonstrated that, for the parameters corresponding to conventional metals, it has the shape of a loop similar to the van der Waals loop. On this basis, it is concluded that hydrogen embrittlement of materials under load is a typical first-order phase transition and, therefore, occurs through nucleation of a new phase. Thermodynamic and kinetic theories of this transition are developed, and time dependences of all the main characteristics of this process are calculated.
Original language | English |
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Pages (from-to) | 1901-1906 |
Number of pages | 6 |
Journal | Physics of the Solid State |
Volume | 51 |
Issue number | 9 |
DOIs | |
State | Published - 2009 |
ID: 75071899