Standard

Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions. / Yakimanskii, Aleksander V.; Bushin, Stanislav V.; Bezrukova, Marina A.; Lezov, Aleksej A.; Gubarev, Aleksander S.; Lebedeva, Elena V.; Akhmadeeva, Lilija I.; Podseval`nikova, Anna N.; Tsvetkov, Nikolaj V.; Koeckelberghs, Guy; Persoons, Andre.

In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 54, No. 9, 2016, p. 875-883.

Research output: Contribution to journal › Article

Harvard

Yakimanskii, AV, Bushin, SV, Bezrukova, MA, Lezov, AA, Gubarev, AS, Lebedeva, EV, Akhmadeeva, LI, Podseval`nikova, AN, Tsvetkov, NV, Koeckelberghs, G & Persoons, A 2016, 'Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions', Journal of Polymer Science, Part B: Polymer Physics, vol. 54, no. 9, pp. 875-883. https://doi.org/10.1002/polb.23986

APA

Yakimanskii, A. V., Bushin, S. V., Bezrukova, M. A., Lezov, A. A., Gubarev, A. S., Lebedeva, E. V., Akhmadeeva, L. I., Podseval`nikova, A. N., Tsvetkov, N. V., Koeckelberghs, G., & Persoons, A. (2016). Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions. Journal of Polymer Science, Part B: Polymer Physics, 54(9), 875-883. https://doi.org/10.1002/polb.23986

Vancouver

Yakimanskii AV, Bushin SV, Bezrukova MA, Lezov AA, Gubarev AS, Lebedeva EV et al. Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions. Journal of Polymer Science, Part B: Polymer Physics. 2016;54(9):875-883. https://doi.org/10.1002/polb.23986

Author

Yakimanskii, Aleksander V. ; Bushin, Stanislav V. ; Bezrukova, Marina A. ; Lezov, Aleksej A. ; Gubarev, Aleksander S. ; Lebedeva, Elena V. ; Akhmadeeva, Lilija I. ; Podseval`nikova, Anna N. ; Tsvetkov, Nikolaj V. ; Koeckelberghs, Guy ; Persoons, Andre. / Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions. In: Journal of Polymer Science, Part B: Polymer Physics. 2016 ; Vol. 54, No. 9. pp. 875-883.

BibTeX

@article{32a775a34dc7415086696821af554d18,
title = "Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions",
abstract = "Conducting polymers demonstrate low solubility in organic solvents. Introducing aliphatic substituents into polymer chains improves their solubility, but may also lead to changes in conformational characteristics of macromolecules. In the present work, the studies of hydrodynamic properties and conformational characteristics of comb-shaped poly(3-hexylthiophene) with aliphatic side substituents were carried out in chloroform solutions. Conformational analysis of the studied macromolecules was performed for the first time using homologous series in a wide range of molecular weights of the polymer in dilute solutions. Hydrodynamic properties of macromolecules were interpreted using the worm-like spherocylinder model (Yamakawa H.) and the straight spherocylinder model (Norisuye T.) The length of a monomer unit projection onto the extended macromolecule (λ = 0.37 nm) was determined experimentally. The following parameters were characterized quantified: equilibrium rigidity (А = 6.7 nm) and hydrodynamic diameter o",
keywords = "poly-(3-hexylthiophene), hydrodynamic properties, DLS, sedimentation",
author = "Yakimanskii, {Aleksander V.} and Bushin, {Stanislav V.} and Bezrukova, {Marina A.} and Lezov, {Aleksej A.} and Gubarev, {Aleksander S.} and Lebedeva, {Elena V.} and Akhmadeeva, {Lilija I.} and Podseval`nikova, {Anna N.} and Tsvetkov, {Nikolaj V.} and Guy Koeckelberghs and Andre Persoons",
year = "2016",
doi = "10.1002/polb.23986",
language = "English",
volume = "54",
pages = "875--883",
journal = "Journal of Polymer Science, Polymer Letters Edition",
issn = "0887-6266",
publisher = "Wiley-Blackwell",
number = "9",

}

RIS

TY - JOUR

T1 - Hydrodynamic properties and conformation of Poly(3-hexylthiophene) in dilute solutions

AU - Yakimanskii, Aleksander V.

AU - Bushin, Stanislav V.

AU - Bezrukova, Marina A.

AU - Lezov, Aleksej A.

AU - Gubarev, Aleksander S.

AU - Lebedeva, Elena V.

AU - Akhmadeeva, Lilija I.

AU - Podseval`nikova, Anna N.

AU - Tsvetkov, Nikolaj V.

AU - Koeckelberghs, Guy

AU - Persoons, Andre

PY - 2016

Y1 - 2016

N2 - Conducting polymers demonstrate low solubility in organic solvents. Introducing aliphatic substituents into polymer chains improves their solubility, but may also lead to changes in conformational characteristics of macromolecules. In the present work, the studies of hydrodynamic properties and conformational characteristics of comb-shaped poly(3-hexylthiophene) with aliphatic side substituents were carried out in chloroform solutions. Conformational analysis of the studied macromolecules was performed for the first time using homologous series in a wide range of molecular weights of the polymer in dilute solutions. Hydrodynamic properties of macromolecules were interpreted using the worm-like spherocylinder model (Yamakawa H.) and the straight spherocylinder model (Norisuye T.) The length of a monomer unit projection onto the extended macromolecule (λ = 0.37 nm) was determined experimentally. The following parameters were characterized quantified: equilibrium rigidity (А = 6.7 nm) and hydrodynamic diameter o

AB - Conducting polymers demonstrate low solubility in organic solvents. Introducing aliphatic substituents into polymer chains improves their solubility, but may also lead to changes in conformational characteristics of macromolecules. In the present work, the studies of hydrodynamic properties and conformational characteristics of comb-shaped poly(3-hexylthiophene) with aliphatic side substituents were carried out in chloroform solutions. Conformational analysis of the studied macromolecules was performed for the first time using homologous series in a wide range of molecular weights of the polymer in dilute solutions. Hydrodynamic properties of macromolecules were interpreted using the worm-like spherocylinder model (Yamakawa H.) and the straight spherocylinder model (Norisuye T.) The length of a monomer unit projection onto the extended macromolecule (λ = 0.37 nm) was determined experimentally. The following parameters were characterized quantified: equilibrium rigidity (А = 6.7 nm) and hydrodynamic diameter o

KW - poly-(3-hexylthiophene)

KW - hydrodynamic properties

KW - DLS

KW - sedimentation

U2 - 10.1002/polb.23986

DO - 10.1002/polb.23986

M3 - Article

VL - 54

SP - 875

EP - 883

JO - Journal of Polymer Science, Polymer Letters Edition

JF - Journal of Polymer Science, Polymer Letters Edition

SN - 0887-6266

IS - 9

ER -

ID: 7548559