Research output: Contribution to journal › Article › peer-review
Hydroarylation of (E)-5-(2-Arylethenyl)-2-methyl-2 H -tetrazoles under Superelectrophilic Activation. / Lisakova, Anna D.; Ryabukhin, Dmitry S.; Trifonov, Rostislav E.; Ostrovskii, Vladimir A.; Boyarskaya, Irina A.; Vasilyev, Aleksander V.
In: Synthesis (Germany), Vol. 49, No. 3, ss-2016-n0434-op, 01.02.2017, p. 579-586.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Hydroarylation of (E)-5-(2-Arylethenyl)-2-methyl-2 H -tetrazoles under Superelectrophilic Activation
AU - Lisakova, Anna D.
AU - Ryabukhin, Dmitry S.
AU - Trifonov, Rostislav E.
AU - Ostrovskii, Vladimir A.
AU - Boyarskaya, Irina A.
AU - Vasilyev, Aleksander V.
N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart · New York-Synthesis 2017.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - The reaction of 5-(2-arylethenyl)-2-methyl-2H-tetrazoles with arenes (benzene, xylenes, tert-butylbenzene, anisole, veratrole, 1,2-dichlorobenzene) under conditions of superelectrophilic activation under the action of Bronsted superacids (CF3SO3H, FSO3H) or strong Lewis acids (AlCl3, AlBr3) leads regioselectively to the products of hydroarylation of the carbon-carbon double bond, viz., 5-(2,2-diarylethenyl)-2-methyl-2H-tetazoles, in yields of up to 95%.
AB - The reaction of 5-(2-arylethenyl)-2-methyl-2H-tetrazoles with arenes (benzene, xylenes, tert-butylbenzene, anisole, veratrole, 1,2-dichlorobenzene) under conditions of superelectrophilic activation under the action of Bronsted superacids (CF3SO3H, FSO3H) or strong Lewis acids (AlCl3, AlBr3) leads regioselectively to the products of hydroarylation of the carbon-carbon double bond, viz., 5-(2,2-diarylethenyl)-2-methyl-2H-tetazoles, in yields of up to 95%.
KW - Bronsted superacid
KW - Friedel-Crafts reaction
KW - hydroarylation
KW - Lewis superacid
KW - superelectrophilic activation
KW - tetrazoles
UR - http://www.scopus.com/inward/record.url?scp=84988661340&partnerID=8YFLogxK
U2 - 10.1055/s-0036-1588884
DO - 10.1055/s-0036-1588884
M3 - Article
AN - SCOPUS:84988661340
VL - 49
SP - 579
EP - 586
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 3
M1 - ss-2016-n0434-op
ER -
ID: 97812675