Research output: Contribution to journal › Article › peer-review
The reaction of CF 3 -propargyl alcohols [ArCCCH(OH)CF 3 ] with arenes under the action of acidic HUSY zeolite CBV-720 was investigated. It was found that the reaction at 100 °C for 1 h gave rise to 3-aryl-1-CF 3 -indenes in up to 83% yield. Electronic characteristics of the reaction key intermediates, mesomeric CF 3 -propargyl-allenyl cations [ArCC-HC + (CF 3 ) ↔ ArC + CCH(CF 3 )], were studied by DFT calculations. A plausible cationic reaction mechanism is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 1215-1224 |
| Number of pages | 10 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 17 |
| Issue number | 5 |
| DOIs | |
| State | Published - 7 Feb 2019 |
ID: 44001636