Research output: Contribution to journal › Article › peer-review
Humic acids isolated from selected soils from the russian arctic and antarctic : Characterization by two-dimensional1H-13C HETCOR and13C CP/Mas NMR spectroscopy. / Polyakov, Vyacheslav; Abakumov, Evgeny V.
In: Geosciences (Switzerland), Vol. 10, No. 1, 15, 01.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Humic acids isolated from selected soils from the russian arctic and antarctic
T2 - Characterization by two-dimensional1H-13C HETCOR and13C CP/Mas NMR spectroscopy
AU - Polyakov, Vyacheslav
AU - Abakumov, Evgeny V.
PY - 2020/1
Y1 - 2020/1
N2 - Here we describe the molecular composition and resistance to decomposition of humic acids isolated from selected soils of the Russian Arctic and Antarctic. The degree of soil organic matter stabilization was assessed using modern instrumental methods: nuclear magnetic resonance spectroscopy (cross peak magic-angle spinning (CP/MAS)13C-NMR and1H-13C heteronuclear-correlation (HETCOR)). Analysis of the humic acids showed that aromatic compounds prevail in the organic matter formed in cryoconites, located on the surfaces of the glaciers. The predominance of aliphatic fragments is revealed in the soils of the Yamal peninsula and Antarctica. This could be caused by sedimentation of fresh organic matter exhibiting low decomposition stage due to the severe climate and processes of hydrogenation in the humic acids, destruction of the C-C bonds, and formation of chains with high hydrogen content. These processes result in formation of aliphatic fragments in the humic acids.
AB - Here we describe the molecular composition and resistance to decomposition of humic acids isolated from selected soils of the Russian Arctic and Antarctic. The degree of soil organic matter stabilization was assessed using modern instrumental methods: nuclear magnetic resonance spectroscopy (cross peak magic-angle spinning (CP/MAS)13C-NMR and1H-13C heteronuclear-correlation (HETCOR)). Analysis of the humic acids showed that aromatic compounds prevail in the organic matter formed in cryoconites, located on the surfaces of the glaciers. The predominance of aliphatic fragments is revealed in the soils of the Yamal peninsula and Antarctica. This could be caused by sedimentation of fresh organic matter exhibiting low decomposition stage due to the severe climate and processes of hydrogenation in the humic acids, destruction of the C-C bonds, and formation of chains with high hydrogen content. These processes result in formation of aliphatic fragments in the humic acids.
KW - Cryoconite
KW - Cryosol
KW - Molecular composition
KW - Ornitogenic soil
KW - Permafrost-affected soils
KW - permafrost-affected soils
KW - PERMAFROST
KW - CARBON
KW - molecular composition
KW - cryosol
KW - ornitogenic soil
KW - LENA RIVER DELTA
KW - ORGANIC-MATTER
KW - CLIMATE-CHANGE
KW - SUBSTANCES
KW - MOLECULAR COMPOSITION
KW - TUNDRA SOILS
KW - RESPIRATION
KW - ELEMENTAL COMPOSITION
KW - cryoconite
UR - http://www.scopus.com/inward/record.url?scp=85078606246&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/be03b5be-0595-3837-9abf-e667ecc8f054/
U2 - 10.3390/geosciences10010015
DO - 10.3390/geosciences10010015
M3 - Article
AN - SCOPUS:85078606246
VL - 10
JO - Geosciences (Switzerland)
JF - Geosciences (Switzerland)
SN - 2076-3263
IS - 1
M1 - 15
ER -
ID: 51416593