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Highly transparent Pb8O7I2, a novel lead oxyiodide. / Charkin, Dmitri O.; Borisov, Artem S.; Kireev, Vadim E.; Kuznetsov, Alexey N.; Umedov, Shorduz; Nazarchuk, Evgeny V.; Bocharov, Vladimir N.; Siidra, Oleg I.

In: Journal of Solid State Chemistry, Vol. 312, 123277, 08.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Charkin, DO, Borisov, AS, Kireev, VE, Kuznetsov, AN, Umedov, S, Nazarchuk, EV, Bocharov, VN & Siidra, OI 2022, 'Highly transparent Pb8O7I2, a novel lead oxyiodide', Journal of Solid State Chemistry, vol. 312, 123277. https://doi.org/10.1016/j.jssc.2022.123277

APA

Charkin, D. O., Borisov, A. S., Kireev, V. E., Kuznetsov, A. N., Umedov, S., Nazarchuk, E. V., Bocharov, V. N., & Siidra, O. I. (2022). Highly transparent Pb8O7I2, a novel lead oxyiodide. Journal of Solid State Chemistry, 312, [123277]. https://doi.org/10.1016/j.jssc.2022.123277

Vancouver

Charkin DO, Borisov AS, Kireev VE, Kuznetsov AN, Umedov S, Nazarchuk EV et al. Highly transparent Pb8O7I2, a novel lead oxyiodide. Journal of Solid State Chemistry. 2022 Aug;312. 123277. https://doi.org/10.1016/j.jssc.2022.123277

Author

Charkin, Dmitri O. ; Borisov, Artem S. ; Kireev, Vadim E. ; Kuznetsov, Alexey N. ; Umedov, Shorduz ; Nazarchuk, Evgeny V. ; Bocharov, Vladimir N. ; Siidra, Oleg I. / Highly transparent Pb8O7I2, a novel lead oxyiodide. In: Journal of Solid State Chemistry. 2022 ; Vol. 312.

BibTeX

@article{c5cd4a8e1fef4232bcf3c725348e593a,
title = "Highly transparent Pb8O7I2, a novel lead oxyiodide",
abstract = "Studies of the oxygen-rich part of the PbO–PbI2 system revealed existence of a novel Pb8O7I2 which can be prepared via both solid-state and hydrothermal routes. The new compound exhibits a new and complex structure type formed by [Pb8O7]2+ rod-like chains formed by OPb4 tetrahedra and OPb3 pyramids. Pb8O7I2 exhibits high transparency in the 550–2000 ​nm range; experimental and quantum chemical data indicate that it is a semiconductor with Eg ​≈ ​2.6 ​eV consistent with the intense yellow color.",
keywords = "Crystal structure, Electronic structure, Lead oxyiodide, Optical spectroscopy",
author = "Charkin, {Dmitri O.} and Borisov, {Artem S.} and Kireev, {Vadim E.} and Kuznetsov, {Alexey N.} and Shorduz Umedov and Nazarchuk, {Evgeny V.} and Bocharov, {Vladimir N.} and Siidra, {Oleg I.}",
note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Inc.",
year = "2022",
month = aug,
doi = "10.1016/j.jssc.2022.123277",
language = "English",
volume = "312",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Highly transparent Pb8O7I2, a novel lead oxyiodide

AU - Charkin, Dmitri O.

AU - Borisov, Artem S.

AU - Kireev, Vadim E.

AU - Kuznetsov, Alexey N.

AU - Umedov, Shorduz

AU - Nazarchuk, Evgeny V.

AU - Bocharov, Vladimir N.

AU - Siidra, Oleg I.

N1 - Publisher Copyright: © 2022 Elsevier Inc.

PY - 2022/8

Y1 - 2022/8

N2 - Studies of the oxygen-rich part of the PbO–PbI2 system revealed existence of a novel Pb8O7I2 which can be prepared via both solid-state and hydrothermal routes. The new compound exhibits a new and complex structure type formed by [Pb8O7]2+ rod-like chains formed by OPb4 tetrahedra and OPb3 pyramids. Pb8O7I2 exhibits high transparency in the 550–2000 ​nm range; experimental and quantum chemical data indicate that it is a semiconductor with Eg ​≈ ​2.6 ​eV consistent with the intense yellow color.

AB - Studies of the oxygen-rich part of the PbO–PbI2 system revealed existence of a novel Pb8O7I2 which can be prepared via both solid-state and hydrothermal routes. The new compound exhibits a new and complex structure type formed by [Pb8O7]2+ rod-like chains formed by OPb4 tetrahedra and OPb3 pyramids. Pb8O7I2 exhibits high transparency in the 550–2000 ​nm range; experimental and quantum chemical data indicate that it is a semiconductor with Eg ​≈ ​2.6 ​eV consistent with the intense yellow color.

KW - Crystal structure

KW - Electronic structure

KW - Lead oxyiodide

KW - Optical spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85131395324&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/67cf3fff-2a31-30df-9a23-2a6407ed05f9/

U2 - 10.1016/j.jssc.2022.123277

DO - 10.1016/j.jssc.2022.123277

M3 - Article

AN - SCOPUS:85131395324

VL - 312

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

M1 - 123277

ER -

ID: 96418988