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Highly Dispersed Cu−NX Moieties Embedded in Graphene : A Promising Electrocatalyst towards the Oxygen Reduction Reaction. / Lu, Xiangyu; Du, Lei; Wang, Dan; Yang, Peixia; Liu, Lilai; Zhang, Jinqiu; An, Maozhong; Levin, Oleg; Wang, Jinpeng; Ge, Liping.

In: ChemElectroChem, Vol. 5, No. 21, 02.11.2018, p. 3323-3329.

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Lu, Xiangyu ; Du, Lei ; Wang, Dan ; Yang, Peixia ; Liu, Lilai ; Zhang, Jinqiu ; An, Maozhong ; Levin, Oleg ; Wang, Jinpeng ; Ge, Liping. / Highly Dispersed Cu−NX Moieties Embedded in Graphene : A Promising Electrocatalyst towards the Oxygen Reduction Reaction. In: ChemElectroChem. 2018 ; Vol. 5, No. 21. pp. 3323-3329.

BibTeX

@article{a698c95107ef42949014255256fa21db,
title = "Highly Dispersed Cu−NX Moieties Embedded in Graphene: A Promising Electrocatalyst towards the Oxygen Reduction Reaction",
abstract = "Transition metal–carbon–nitrogen catalysts for the oxygen reduction reaction (ORR) are promising and challenging. Cu is a potential transition metal to form efficient ORR catalysts for fuel cells. Herein, a facile method is developed to synthesize a highly dispersed Cu−NX and N-doped graphene (Cu−N−G) catalyst. The Cu−N−G catalyst shows a half-wave potential (E1/2) of 0.859 V, which is comparable to the commercial Pt/C catalyst (0.856 V), and is among the best compared with the previously reported Cu-based materials. In addition, such a catalyst shows good stability and methanol tolerance in alkaline media. A synergy of doped N (pyridinic and graphitic N) and Cu−NX moieties as well as the pore structure are revealed to account for the enhanced ORR activity.",
keywords = "N-doped graphene, Pt-free catalysts, copper, fuel cells, oxygen reduction reaction",
author = "Xiangyu Lu and Lei Du and Dan Wang and Peixia Yang and Lilai Liu and Jinqiu Zhang and Maozhong An and Oleg Levin and Jinpeng Wang and Liping Ge",
year = "2018",
month = nov,
day = "2",
doi = "10.1 002/celc.201800657",
language = "English",
volume = "5",
pages = "3323--3329",
journal = "ChemElectroChem",
issn = "2196-0216",
publisher = "Wiley-Blackwell",
number = "21",

}

RIS

TY - JOUR

T1 - Highly Dispersed Cu−NX Moieties Embedded in Graphene

T2 - A Promising Electrocatalyst towards the Oxygen Reduction Reaction

AU - Lu, Xiangyu

AU - Du, Lei

AU - Wang, Dan

AU - Yang, Peixia

AU - Liu, Lilai

AU - Zhang, Jinqiu

AU - An, Maozhong

AU - Levin, Oleg

AU - Wang, Jinpeng

AU - Ge, Liping

PY - 2018/11/2

Y1 - 2018/11/2

N2 - Transition metal–carbon–nitrogen catalysts for the oxygen reduction reaction (ORR) are promising and challenging. Cu is a potential transition metal to form efficient ORR catalysts for fuel cells. Herein, a facile method is developed to synthesize a highly dispersed Cu−NX and N-doped graphene (Cu−N−G) catalyst. The Cu−N−G catalyst shows a half-wave potential (E1/2) of 0.859 V, which is comparable to the commercial Pt/C catalyst (0.856 V), and is among the best compared with the previously reported Cu-based materials. In addition, such a catalyst shows good stability and methanol tolerance in alkaline media. A synergy of doped N (pyridinic and graphitic N) and Cu−NX moieties as well as the pore structure are revealed to account for the enhanced ORR activity.

AB - Transition metal–carbon–nitrogen catalysts for the oxygen reduction reaction (ORR) are promising and challenging. Cu is a potential transition metal to form efficient ORR catalysts for fuel cells. Herein, a facile method is developed to synthesize a highly dispersed Cu−NX and N-doped graphene (Cu−N−G) catalyst. The Cu−N−G catalyst shows a half-wave potential (E1/2) of 0.859 V, which is comparable to the commercial Pt/C catalyst (0.856 V), and is among the best compared with the previously reported Cu-based materials. In addition, such a catalyst shows good stability and methanol tolerance in alkaline media. A synergy of doped N (pyridinic and graphitic N) and Cu−NX moieties as well as the pore structure are revealed to account for the enhanced ORR activity.

KW - N-doped graphene

KW - Pt-free catalysts

KW - copper

KW - fuel cells

KW - oxygen reduction reaction

UR - http://www.scopus.com/inward/record.url?scp=85052513778&partnerID=8YFLogxK

U2 - 10.1 002/celc.201800657

DO - 10.1 002/celc.201800657

M3 - Article

AN - SCOPUS:85052513778

VL - 5

SP - 3323

EP - 3329

JO - ChemElectroChem

JF - ChemElectroChem

SN - 2196-0216

IS - 21

ER -

ID: 34574177