High Temperature Study of Oxide Systems: Thermal Analysis and Knudsen Effusion Mass Spectrometry

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High Temperature Study of Oxide Systems: Thermal Analysis and Knudsen Effusion Mass Spectrometry. / Stolyarova, V. L.; Vorozhtcov, V. A.

In: Russian Journal of Physical Chemistry A, Vol. 94, No. 13, 12.2020, p. 2640-2647.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{99184413318a48d8856b94fdd9c92977,

title = "High Temperature Study of Oxide Systems: Thermal Analysis and Knudsen Effusion Mass Spectrometry",

abstract = "Abstract: Advantages and comparison of thermal analysis (TA) and Knudsen effusion mass spectrometry (KEMS) were discussed for the investigation of high temperature behavior of oxide systems such as ceramics and glass-forming melts. This brief overview proposes filling the gap by considering various approaches of interaction between the TA and KEMS data. The reliability of experimental data found using both methods is critically analyzed for thermodynamic values of the lanthanoid hafnates obtained by DSC and KEMS and mass losses of the samples in the Bi2O3–P2O5–SiO2 system found by thermogravimetry and KEMS. Recent achievements in experimental installations for these methods were also noted.",

keywords = "DSC, glass-forming melts, Knudsen effusion mass spectrometry, oxide ceramics, thermal analysis, thermodynamics",

author = "Stolyarova, {V. L.} and Vorozhtcov, {V. A.}",

note = "Funding Information: This study was funded by the Russian Foundation for Basic Research (grant nos. 13-03-00718 and 19-03-00721). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1134/S0036024420130257",

language = "English",

volume = "94",

pages = "2640--2647",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "13",

}

RIS

TY - JOUR

T1 - High Temperature Study of Oxide Systems: Thermal Analysis and Knudsen Effusion Mass Spectrometry

AU - Stolyarova, V. L.

AU - Vorozhtcov, V. A.

N1 - Funding Information: This study was funded by the Russian Foundation for Basic Research (grant nos. 13-03-00718 and 19-03-00721). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Abstract: Advantages and comparison of thermal analysis (TA) and Knudsen effusion mass spectrometry (KEMS) were discussed for the investigation of high temperature behavior of oxide systems such as ceramics and glass-forming melts. This brief overview proposes filling the gap by considering various approaches of interaction between the TA and KEMS data. The reliability of experimental data found using both methods is critically analyzed for thermodynamic values of the lanthanoid hafnates obtained by DSC and KEMS and mass losses of the samples in the Bi2O3–P2O5–SiO2 system found by thermogravimetry and KEMS. Recent achievements in experimental installations for these methods were also noted.

AB - Abstract: Advantages and comparison of thermal analysis (TA) and Knudsen effusion mass spectrometry (KEMS) were discussed for the investigation of high temperature behavior of oxide systems such as ceramics and glass-forming melts. This brief overview proposes filling the gap by considering various approaches of interaction between the TA and KEMS data. The reliability of experimental data found using both methods is critically analyzed for thermodynamic values of the lanthanoid hafnates obtained by DSC and KEMS and mass losses of the samples in the Bi2O3–P2O5–SiO2 system found by thermogravimetry and KEMS. Recent achievements in experimental installations for these methods were also noted.

KW - DSC

KW - glass-forming melts

KW - Knudsen effusion mass spectrometry

KW - oxide ceramics

KW - thermal analysis

KW - thermodynamics

UR - http://www.scopus.com/inward/record.url?scp=85097045849&partnerID=8YFLogxK

U2 - 10.1134/S0036024420130257

DO - 10.1134/S0036024420130257

M3 - Article

AN - SCOPUS:85097045849

VL - 94

SP - 2640

EP - 2647

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 13

ER -

ID: 71530520