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Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines. / Щербаков, Николай Викторович; Дубовцев, Алексей Юрьевич; Дарьин, Дмитрий Викторович; Кукушкин, Вадим Юрьевич.

In: The Journal of organic chemistry, Vol. 86, No. 10, 07.05.2021, p. 7218-7228.

Research output: Contribution to journal › Article › peer-review

Harvard

Щербаков, НВ, Дубовцев, АЮ, Дарьин, ДВ & Кукушкин, ВЮ 2021, 'Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines', The Journal of organic chemistry, vol. 86, no. 10, pp. 7218-7228. https://doi.org/10.1021/acs.joc.1c00558

APA

Щербаков, Н. В., Дубовцев, А. Ю., Дарьин, Д. В., & Кукушкин, В. Ю. (2021). Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines. The Journal of organic chemistry, 86(10), 7218-7228. https://doi.org/10.1021/acs.joc.1c00558

Vancouver

Щербаков НВ, Дубовцев АЮ, Дарьин ДВ, Кукушкин ВЮ. Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines. The Journal of organic chemistry. 2021 May 7;86(10):7218-7228. https://doi.org/10.1021/acs.joc.1c00558

Author

Щербаков, Николай Викторович ; Дубовцев, Алексей Юрьевич ; Дарьин, Дмитрий Викторович ; Кукушкин, Вадим Юрьевич. / Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines. In: The Journal of organic chemistry. 2021 ; Vol. 86, No. 10. pp. 7218-7228.

BibTeX

@article{5e28559fb75c4847aa4cb64736952e5a,
title = "Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines",
abstract = "Gold(I)-catalyzed hetero-tetradehydro-Diels-Alder cycloaddition of enynamides and cyanamides comprises an efficient route to diversely substituted 2,6-diaminopyridines (28 examples; yields up to 99%). The reaction proceeds under very mild conditions (DCM, rt) with high functional group tolerance. The obtained 2,6-diaminopyridines represent a useful synthetic platform with an easily modulated substitution pattern for subsequent functionalizations of both the pyridine core and the N-substituents.",
author = "Щербаков, {Николай Викторович} and Дубовцев, {Алексей Юрьевич} and Дарьин, {Дмитрий Викторович} and Кукушкин, {Вадим Юрьевич}",
note = "Publisher Copyright: {\textcopyright}",
year = "2021",
month = may,
day = "7",
doi = "10.1021/acs.joc.1c00558",
language = "English",
volume = "86",
pages = "7218--7228",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Hetero-Tetradehydro-Diels–Alder Cycloaddition of Enynamides and Cyanamides: Gold-Catalyzed Generation of Diversely Substituted 2,6-Diaminopyridines

AU - Щербаков, Николай Викторович

AU - Дубовцев, Алексей Юрьевич

AU - Дарьин, Дмитрий Викторович

AU - Кукушкин, Вадим Юрьевич

N1 - Publisher Copyright: ©

PY - 2021/5/7

Y1 - 2021/5/7

N2 - Gold(I)-catalyzed hetero-tetradehydro-Diels-Alder cycloaddition of enynamides and cyanamides comprises an efficient route to diversely substituted 2,6-diaminopyridines (28 examples; yields up to 99%). The reaction proceeds under very mild conditions (DCM, rt) with high functional group tolerance. The obtained 2,6-diaminopyridines represent a useful synthetic platform with an easily modulated substitution pattern for subsequent functionalizations of both the pyridine core and the N-substituents.

AB - Gold(I)-catalyzed hetero-tetradehydro-Diels-Alder cycloaddition of enynamides and cyanamides comprises an efficient route to diversely substituted 2,6-diaminopyridines (28 examples; yields up to 99%). The reaction proceeds under very mild conditions (DCM, rt) with high functional group tolerance. The obtained 2,6-diaminopyridines represent a useful synthetic platform with an easily modulated substitution pattern for subsequent functionalizations of both the pyridine core and the N-substituents.

UR - http://www.scopus.com/inward/record.url?scp=85106537286&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/a818f40d-d1f4-3ef4-8325-f40e397bdae8/

U2 - 10.1021/acs.joc.1c00558

DO - 10.1021/acs.joc.1c00558

M3 - Article

VL - 86

SP - 7218

EP - 7228

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 10

ER -

ID: 85051470