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Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1016/j.inoche.2019.05.018
Final published version

Sergey A. Adonin
Alexander S. Novikov
Maxim N. Sokolov
Vladimir P. Fedin

Heteroleptic complex of copper [Cu ₂ (IOAc) ₄ (3,5-ClPy) ₂ ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).

Original language	English
Pages (from-to)	221-224
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	105
DOIs	https://doi.org/10.1016/j.inoche.2019.05.018
State	Published - 1 Jul 2019

Scopus subject areas

Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry

Research areas

Carboxylate complexes, Copper, Crystal structure, Halogen bonding, Supramolecular contacts, HALIDES, INTERPLAY, S-ALKYL DERIVATIVES, BEHAVIOR, ACID. CRYSTAL-STRUCTURE, BINUCLEAR COPPER(II)-COMPLEX, LIGANDS, MAGNETIC-PROPERTIES, METAL-IONS, ARCHITECTURES

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