DOI

Heteroleptic Cu(I) complexes with 1,10-octachlorophenanthroline (OCP) [Cu2(OCP)2×2] (X = Br (1), I (2)) were prepared and characterized by X-ray diffractometry (XRD) and thermogravimetric analysis (TGA). In the structures of 1 and 2, there are Cl•••Br and Cl•••I non-covalent interactions which can be regarded as halogen bonding (XB); according to DFT calculations, their energies are up to 2.1 kcal/mol.

Original languageEnglish
Article number130199
Number of pages6
JournalJournal of Molecular Structure
Volume1234
DOIs
StatePublished - 15 Jun 2021

    Research areas

  • Copper, N-donor ligands, Non-covalent interactions, X-ray diffractometry, COPPER(I), POLYMERS, LUMINESCENCE, LANTHANIDE FLUOROBENZOATES, OCTACHLORO-1,10-PHENANTHROLINE, LIGAND, HALOGEN BOND, SOLID-STATE

    Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Inorganic Chemistry
  • Organic Chemistry

ID: 77246457