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Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives. / Rajakumar, K.; Zherebtsov, D. A. ; Nayfert, S. A.; Osipov, A. A. ; Adonin, S. A.; Spiridonova, D. V.

In: Crystallography Reports, Vol. 69, No. 4, 01.08.2024, p. 500–506.

Research output: Contribution to journal › Article › peer-review

Harvard

Rajakumar, K, Zherebtsov, DA, Nayfert, SA, Osipov, AA, Adonin, SA & Spiridonova, DV 2024, 'Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives', Crystallography Reports, vol. 69, no. 4, pp. 500–506. https://doi.org/10.1134/s106377452460131x

APA

Rajakumar, K., Zherebtsov, D. A., Nayfert, S. A., Osipov, A. A., Adonin, S. A., & Spiridonova, D. V. (2024). Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives. Crystallography Reports, 69(4), 500–506. https://doi.org/10.1134/s106377452460131x

Vancouver

Rajakumar K, Zherebtsov DA, Nayfert SA, Osipov AA, Adonin SA, Spiridonova DV. Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives. Crystallography Reports. 2024 Aug 1;69(4):500–506. https://doi.org/10.1134/s106377452460131x

Author

Rajakumar, K. ; Zherebtsov, D. A. ; Nayfert, S. A. ; Osipov, A. A. ; Adonin, S. A. ; Spiridonova, D. V. / Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives. In: Crystallography Reports. 2024 ; Vol. 69, No. 4. pp. 500–506.

BibTeX

@article{a45c5bd5e4a34382b6d326a004ac76bb,
title = "Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives",
abstract = "Abstract: 1,4-Di(bromomethyl)-2,5-diiodobenzene (1), 2,5-diiodo-1,4-di(hydroxymethyl)benzene diacetate (2), and 1,1'-[(2,5-diiodo-1,4-phenylene)bis(methylene)]dipyridinium diiodide (3) were synthesized, and their crystallographic data are reported. All three crystal structures are characterized by the stacked packing of the planar molecules and the presence of halogen bonds I⋅⋅⋅Br, I⋅⋅⋅O, and I⋅⋅⋅I, respectively. The largest number of halogen bonds was found in compound 1, in which there are two I⋅⋅⋅Br bonds per halogen atom. Compounds 2 and 3 contain one halogen bond per halogen atom; however, these bonds are significantly shorter than those in compound 1. All crystals were studied by IR spectroscopy and simultaneous thermal analysis. Compound 1, which has no ionic or hydrogen bonds, melts at a higher temperature compared to ionic compound 3 (218 and 200°С, respectively) due to the presence of a larger number of intermolecular halogen bonds. Compound 2 melts at a lower temperature (151°С), which is characteristic of esters.",
author = "K. Rajakumar and Zherebtsov, {D. A.} and Nayfert, {S. A.} and Osipov, {A. A.} and Adonin, {S. A.} and Spiridonova, {D. V.}",
year = "2024",
month = aug,
day = "1",
doi = "10.1134/s106377452460131x",
language = "English",
volume = "69",
pages = "500–506",
journal = "Crystallography Reports",
issn = "1063-7745",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Halogen Bonds in 2,5-Diiodo-1,4-dimethylbenezene Derivatives

AU - Rajakumar, K.

AU - Zherebtsov, D. A.

AU - Nayfert, S. A.

AU - Osipov, A. A.

AU - Adonin, S. A.

AU - Spiridonova, D. V.

PY - 2024/8/1

Y1 - 2024/8/1

N2 - Abstract: 1,4-Di(bromomethyl)-2,5-diiodobenzene (1), 2,5-diiodo-1,4-di(hydroxymethyl)benzene diacetate (2), and 1,1'-[(2,5-diiodo-1,4-phenylene)bis(methylene)]dipyridinium diiodide (3) were synthesized, and their crystallographic data are reported. All three crystal structures are characterized by the stacked packing of the planar molecules and the presence of halogen bonds I⋅⋅⋅Br, I⋅⋅⋅O, and I⋅⋅⋅I, respectively. The largest number of halogen bonds was found in compound 1, in which there are two I⋅⋅⋅Br bonds per halogen atom. Compounds 2 and 3 contain one halogen bond per halogen atom; however, these bonds are significantly shorter than those in compound 1. All crystals were studied by IR spectroscopy and simultaneous thermal analysis. Compound 1, which has no ionic or hydrogen bonds, melts at a higher temperature compared to ionic compound 3 (218 and 200°С, respectively) due to the presence of a larger number of intermolecular halogen bonds. Compound 2 melts at a lower temperature (151°С), which is characteristic of esters.

AB - Abstract: 1,4-Di(bromomethyl)-2,5-diiodobenzene (1), 2,5-diiodo-1,4-di(hydroxymethyl)benzene diacetate (2), and 1,1'-[(2,5-diiodo-1,4-phenylene)bis(methylene)]dipyridinium diiodide (3) were synthesized, and their crystallographic data are reported. All three crystal structures are characterized by the stacked packing of the planar molecules and the presence of halogen bonds I⋅⋅⋅Br, I⋅⋅⋅O, and I⋅⋅⋅I, respectively. The largest number of halogen bonds was found in compound 1, in which there are two I⋅⋅⋅Br bonds per halogen atom. Compounds 2 and 3 contain one halogen bond per halogen atom; however, these bonds are significantly shorter than those in compound 1. All crystals were studied by IR spectroscopy and simultaneous thermal analysis. Compound 1, which has no ionic or hydrogen bonds, melts at a higher temperature compared to ionic compound 3 (218 and 200°С, respectively) due to the presence of a larger number of intermolecular halogen bonds. Compound 2 melts at a lower temperature (151°С), which is characteristic of esters.

UR - https://www.mendeley.com/catalogue/f34cae3a-0aeb-3556-b3fc-2f4f5d5540eb/

U2 - 10.1134/s106377452460131x

DO - 10.1134/s106377452460131x

M3 - Article

VL - 69

SP - 500

EP - 506

JO - Crystallography Reports

JF - Crystallography Reports

SN - 1063-7745

IS - 4

ER -

ID: 123117423