DOI

Supramolecular hybrid (2-ClPy)2{[TeBr6](Br2)} (1) was prepared by the reaction of TeO2, Br2 and 2-chloropyridinium in HBr. In the structure, mononuclear [TeBr6]2− units are connected by {Br2} linkers into 1D zigzag-shaped infinite chains. Energies of halogen bonding were estimated by theoretical methods (1.3–3.3 kcal/mol).

Original languageEnglish
Pages (from-to)1890-1898
Number of pages9
JournalJournal of Coordination Chemistry
Volume72
Issue number11
DOIs
StatePublished - 3 Jun 2019

    Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry

    Research areas

  • halide complexes, halogen bonding, Polyhalide, supramolecular contacts, tellurium, FE CONTACTS, INTERPLAY, COMPLEXES, CRYSTAL-STRUCTURES, NETWORKS, NONCOVALENT INTERACTIONS, CENTERS, PREDICTION, HYDROGEN

ID: 43749528