Halogen bonding in isostructural Co(II) complexes with 2-halopyridines

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.3390/cryst10040289
Final published version

Sergey A. Adonin
Mikhail A. Bondarenko
Alexander S. Novikov
Maxim N. Sokolov

Three complexes [Co(2-XPy)₂Cl₂] (X = Cl, Br, and I) were prepared and characterized, representing a rare case of isostructurality within the Cl-Br-I row. The nature of halogen bonding (XB) in a solid state was studied by DFT calculations, revealing a tendency of XB energy growth for heavier halogens.

Original language	English
Article number	289
Number of pages	7
Journal	Crystals
Volume	10
Issue number	4
DOIs	https://doi.org/10.3390/cryst10040289
State	Published - Apr 2020

Scopus subject areas

Condensed Matter Physics
Chemical Engineering(all)
Materials Science(all)
Inorganic Chemistry

Research areas

Cobalt, DFT calculations, Halogen bonding, Pyridines, FE CONTACTS, CRYSTAL-STRUCTURES, CL, cobalt, NONCOVALENT INTERACTIONS, PYRIDINE-TYPE COMPLEXES, DENSITY, TRANSITION-METAL HALIDES, HYDROGEN, INFRARED-SPECTRA, pyridines, MAGNETIC-PROPERTIES, halogen bonding

ID: 53562220