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H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys. / Vyvodtceva, A.V.; Shelyapina, M.G.; Privalov, A.F.; Chernyshev, Y.S.; Fruchart, D.

In: Journal of Alloys and Compounds, Vol. 614, 2014, p. 364-367.

Research output: Contribution to journal › Article

Harvard

Vyvodtceva, AV, Shelyapina, MG, Privalov, AF, Chernyshev, YS & Fruchart, D 2014, 'H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys', Journal of Alloys and Compounds, vol. 614, pp. 364-367. https://doi.org/10.1016/j.jallcom.2014.06.023

APA

Vyvodtceva, A. V., Shelyapina, M. G., Privalov, A. F., Chernyshev, Y. S., & Fruchart, D. (2014). H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys. Journal of Alloys and Compounds, 614, 364-367. https://doi.org/10.1016/j.jallcom.2014.06.023

Vancouver

Vyvodtceva AV, Shelyapina MG, Privalov AF, Chernyshev YS, Fruchart D. H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys. Journal of Alloys and Compounds. 2014;614:364-367. https://doi.org/10.1016/j.jallcom.2014.06.023

Author

Vyvodtceva, A.V. ; Shelyapina, M.G. ; Privalov, A.F. ; Chernyshev, Y.S. ; Fruchart, D. / H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys. In: Journal of Alloys and Compounds. 2014 ; Vol. 614. pp. 364-367.

BibTeX

@article{6a5a84ad1cc248338ff9c0727bd6a681,
title = "H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys",
abstract = "Here we report on the results of proton NMR study of hydrogen self-diffusion in hydrides of Ti-V-Cr alloys of different composition, pure and with 4 wt.% of Zr7Ni10 additives, namely, TiV0.8Cr1.2H5.29, Ti0.5V1.9Cr0.6H5.03 and Ti0.33V1.27Cr1.4H1.13. The measurements have been made using the static field gradient nuclear magnetic resonance technique. The hydrogen self-diffusion coefficient at room temperature lies within the range of 1.4 ÷ 3.7 ×10–11 m2/s. The activation energy Ea strongly depends on the both composition and structure type of the hydride. The samples with bcc structure (and with the lowest hydrogen concentration) exhibit the highest Ea value of 0.2 eV. For the samples with fcc structure the Ea value is lower and decreases with increasing the vanadium fraction. The influence of Zr7Ni10 additives on the measured parameters is also discussed.",
keywords = "Metal hydrides, Diffusion, Nuclear resonances",
author = "A.V. Vyvodtceva and M.G. Shelyapina and A.F. Privalov and Y.S. Chernyshev and D. Fruchart",
year = "2014",
doi = "10.1016/j.jallcom.2014.06.023",
language = "English",
volume = "614",
pages = "364--367",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - H-1 NMR study of hydrogen self-diffusion in ternary Ti-V-Cr alloys

AU - Vyvodtceva, A.V.

AU - Shelyapina, M.G.

AU - Privalov, A.F.

AU - Chernyshev, Y.S.

AU - Fruchart, D.

PY - 2014

Y1 - 2014

N2 - Here we report on the results of proton NMR study of hydrogen self-diffusion in hydrides of Ti-V-Cr alloys of different composition, pure and with 4 wt.% of Zr7Ni10 additives, namely, TiV0.8Cr1.2H5.29, Ti0.5V1.9Cr0.6H5.03 and Ti0.33V1.27Cr1.4H1.13. The measurements have been made using the static field gradient nuclear magnetic resonance technique. The hydrogen self-diffusion coefficient at room temperature lies within the range of 1.4 ÷ 3.7 ×10–11 m2/s. The activation energy Ea strongly depends on the both composition and structure type of the hydride. The samples with bcc structure (and with the lowest hydrogen concentration) exhibit the highest Ea value of 0.2 eV. For the samples with fcc structure the Ea value is lower and decreases with increasing the vanadium fraction. The influence of Zr7Ni10 additives on the measured parameters is also discussed.

AB - Here we report on the results of proton NMR study of hydrogen self-diffusion in hydrides of Ti-V-Cr alloys of different composition, pure and with 4 wt.% of Zr7Ni10 additives, namely, TiV0.8Cr1.2H5.29, Ti0.5V1.9Cr0.6H5.03 and Ti0.33V1.27Cr1.4H1.13. The measurements have been made using the static field gradient nuclear magnetic resonance technique. The hydrogen self-diffusion coefficient at room temperature lies within the range of 1.4 ÷ 3.7 ×10–11 m2/s. The activation energy Ea strongly depends on the both composition and structure type of the hydride. The samples with bcc structure (and with the lowest hydrogen concentration) exhibit the highest Ea value of 0.2 eV. For the samples with fcc structure the Ea value is lower and decreases with increasing the vanadium fraction. The influence of Zr7Ni10 additives on the measured parameters is also discussed.

KW - Metal hydrides

KW - Diffusion

KW - Nuclear resonances

U2 - 10.1016/j.jallcom.2014.06.023

DO - 10.1016/j.jallcom.2014.06.023

M3 - Article

VL - 614

SP - 364

EP - 367

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

ER -

ID: 7005274