Green-light emitting norbornene based terbium-containing copolymers. Synthesis, photo- and electroluminescent properties

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Green-light emitting norbornene based terbium-containing copolymers. Synthesis, photo- and electroluminescent properties. / Bochkarev, Leonid N.; Rozhkov, Anton V.; Ilichev, Vasilii A.; Abakumov, Gleb A.; Bochkarev, Mikhail N.

In: Synthetic Metals, Vol. 190, 01.04.2014, p. 86-91.

Research output: Contribution to journal › Article › peer-review

Author

Bochkarev, Leonid N. ; Rozhkov, Anton V. ; Ilichev, Vasilii A. ; Abakumov, Gleb A. ; Bochkarev, Mikhail N. / Green-light emitting norbornene based terbium-containing copolymers. Synthesis, photo- and electroluminescent properties. In: Synthetic Metals. 2014 ; Vol. 190. pp. 86-91.

BibTeX

@article{b0f2460e60474a4a832f00dec88ba104,

title = "Green-light emitting norbornene based terbium-containing copolymers. Synthesis, photo- and electroluminescent properties",

abstract = "New terbium-containing copolymers were prepared by ring-opening metathesis copolymerization (ROMP) of norbornene substituted terbium complex Tb(L1) 2(L2)(TPPO)2 (L1 = 1-phenyl-3-methyl-4-isobutyryl-5- pyrazolonato, L2 = 1-phenyl-3-methyl-4-(5-bicyclo[2.2.1]hept-5-en-2-yl)-5- pyrazolonato, TPPO = triphenylphosphine oxide) and carbazole-containing norbornene derivatives. The photoluminescence (PL) spectra of the copolymers contained strong narrow bands of terbium ion at 492 (5D4 → 7F6), 550 (5D4 → 7F6), 586 (5D4 → 7F4), 624 (5D4 → 7F3) nm and emission in the region of 350-450 nm assigned to copolymer matrixes. The electroluminescence (EL) spectrum of the tree-layer device of configuration of ITO/Tb-copolymer(40 nm)/BATH(30 nm)/Alq 3(30 nm)/Yb revealed intense emission bands of Tb(III) ions and a broad band at ca. 520 nm of low intensity attributed to emission from triplet level of carbazole groups. The maximum luminance of 70 cd/m2 at 17.5 V, the maximum current efficiency of 0.56 cd/A at 11 V and the maximum power efficiency of 0.16 lm/w at 11 V were achieved. The CIE coordinates (0.28, 0.47) were corresponded to green color and independent on driving voltage.",

keywords = "Copolymer, Electroluminescence, Photoluminescence, ROMP, Terbium",

author = "Bochkarev, {Leonid N.} and Rozhkov, {Anton V.} and Ilichev, {Vasilii A.} and Abakumov, {Gleb A.} and Bochkarev, {Mikhail N.}",

year = "2014",

month = apr,

day = "1",

doi = "10.1016/j.synthmet.2014.02.007",

language = "English",

volume = "190",

pages = "86--91",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Green-light emitting norbornene based terbium-containing copolymers. Synthesis, photo- and electroluminescent properties

AU - Bochkarev, Leonid N.

AU - Rozhkov, Anton V.

AU - Ilichev, Vasilii A.

AU - Abakumov, Gleb A.

AU - Bochkarev, Mikhail N.

PY - 2014/4/1

Y1 - 2014/4/1

N2 - New terbium-containing copolymers were prepared by ring-opening metathesis copolymerization (ROMP) of norbornene substituted terbium complex Tb(L1) 2(L2)(TPPO)2 (L1 = 1-phenyl-3-methyl-4-isobutyryl-5- pyrazolonato, L2 = 1-phenyl-3-methyl-4-(5-bicyclo[2.2.1]hept-5-en-2-yl)-5- pyrazolonato, TPPO = triphenylphosphine oxide) and carbazole-containing norbornene derivatives. The photoluminescence (PL) spectra of the copolymers contained strong narrow bands of terbium ion at 492 (5D4 → 7F6), 550 (5D4 → 7F6), 586 (5D4 → 7F4), 624 (5D4 → 7F3) nm and emission in the region of 350-450 nm assigned to copolymer matrixes. The electroluminescence (EL) spectrum of the tree-layer device of configuration of ITO/Tb-copolymer(40 nm)/BATH(30 nm)/Alq 3(30 nm)/Yb revealed intense emission bands of Tb(III) ions and a broad band at ca. 520 nm of low intensity attributed to emission from triplet level of carbazole groups. The maximum luminance of 70 cd/m2 at 17.5 V, the maximum current efficiency of 0.56 cd/A at 11 V and the maximum power efficiency of 0.16 lm/w at 11 V were achieved. The CIE coordinates (0.28, 0.47) were corresponded to green color and independent on driving voltage.

AB - New terbium-containing copolymers were prepared by ring-opening metathesis copolymerization (ROMP) of norbornene substituted terbium complex Tb(L1) 2(L2)(TPPO)2 (L1 = 1-phenyl-3-methyl-4-isobutyryl-5- pyrazolonato, L2 = 1-phenyl-3-methyl-4-(5-bicyclo[2.2.1]hept-5-en-2-yl)-5- pyrazolonato, TPPO = triphenylphosphine oxide) and carbazole-containing norbornene derivatives. The photoluminescence (PL) spectra of the copolymers contained strong narrow bands of terbium ion at 492 (5D4 → 7F6), 550 (5D4 → 7F6), 586 (5D4 → 7F4), 624 (5D4 → 7F3) nm and emission in the region of 350-450 nm assigned to copolymer matrixes. The electroluminescence (EL) spectrum of the tree-layer device of configuration of ITO/Tb-copolymer(40 nm)/BATH(30 nm)/Alq 3(30 nm)/Yb revealed intense emission bands of Tb(III) ions and a broad band at ca. 520 nm of low intensity attributed to emission from triplet level of carbazole groups. The maximum luminance of 70 cd/m2 at 17.5 V, the maximum current efficiency of 0.56 cd/A at 11 V and the maximum power efficiency of 0.16 lm/w at 11 V were achieved. The CIE coordinates (0.28, 0.47) were corresponded to green color and independent on driving voltage.

KW - Copolymer

KW - Electroluminescence

KW - Photoluminescence

KW - ROMP

KW - Terbium

UR - http://www.scopus.com/inward/record.url?scp=84897677665&partnerID=8YFLogxK

U2 - 10.1016/j.synthmet.2014.02.007

DO - 10.1016/j.synthmet.2014.02.007

M3 - Article

AN - SCOPUS:84897677665

VL - 190

SP - 86

EP - 91

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

ER -

ID: 39928717