Research output: Contribution to journal › Article
Graphene: Synthesis and features of electronic structure. / Shikin, A.M.; Rybkin, A.G.; Marchenko, D.E.; Popova, (Rybkina) A.A.; Varykhalov, A.V.; Rader, O.
In: Nanotechnologies in Russia, Vol. 6, No. 9-10, 2011, p. 625-632.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Graphene: Synthesis and features of electronic structure
AU - Shikin, A.M.
AU - Rybkin, A.G.
AU - Marchenko, D.E.
AU - Popova, (Rybkina) A.A.
AU - Varykhalov, A.V.
AU - Rader, O.
PY - 2011
Y1 - 2011
N2 - Changes in electronic structure of valence band and the corresponding dispersion dependences of the electron states of graphene synthesized by a cracking catalytic reaction of propylene at the surface of Ni(111) thin layers and subsequent intercalation of Au atoms underneath the formed monolayer of graphene have measured and analyzed using angle-resolved photoelectron spectroscopy. It is shown that this technique of graphene synthesis causes the formation of a monolayer graphene cover over large areas with feature of the electrobic structure typical for a quasifree graphene: a linear dispersion of graphene n states in region of the point K of Brillouin zone with the Dirac point localization near the Fermi level.It was estabilished that contact between the graphene monolayer and the intercalated Au layer additionally causes a substrate-induced spin-orbital splitting of graphene n states, which also occurs in the region of dispersion-dependence linearity.
AB - Changes in electronic structure of valence band and the corresponding dispersion dependences of the electron states of graphene synthesized by a cracking catalytic reaction of propylene at the surface of Ni(111) thin layers and subsequent intercalation of Au atoms underneath the formed monolayer of graphene have measured and analyzed using angle-resolved photoelectron spectroscopy. It is shown that this technique of graphene synthesis causes the formation of a monolayer graphene cover over large areas with feature of the electrobic structure typical for a quasifree graphene: a linear dispersion of graphene n states in region of the point K of Brillouin zone with the Dirac point localization near the Fermi level.It was estabilished that contact between the graphene monolayer and the intercalated Au layer additionally causes a substrate-induced spin-orbital splitting of graphene n states, which also occurs in the region of dispersion-dependence linearity.
KW - graphene
KW - electronic structure of valence band
KW - intercalation
KW - angle-resolved photoelectron spectroscopy
KW - spin-orbital splitting of n states
U2 - DOI: 10.1134/S1995078011050132
DO - DOI: 10.1134/S1995078011050132
M3 - Article
VL - 6
SP - 625
EP - 632
JO - Nanobiotechnology Reports
JF - Nanobiotechnology Reports
SN - 2635-1676
IS - 9-10
ER -
ID: 5292489