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Gold-catalyzed O-transfer involving alkynes and nitriles as a straightforward diazo-free route to oxazoles. / Дубовцев, Алексей Юрьевич.

In: Mendeleev Communications, Vol. 35, No. 6, 2025, p. 627–635.

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@article{f05fb8878b784570aff4d39718bf1a7a,
title = "Gold-catalyzed O-transfer involving alkynes and nitriles as a straightforward diazo-free route to oxazoles",
abstract = "In the recent years, the synthesis of oxazoles via (2 + 2 + 1) gold-catalyzed oxygen-transfer reactions involving alkynes and nitriles has become a dynamic field of study. The practical utility of this straightforward diazo-free method has been illustrated through a number of publications, among which are findings from our research group. This focus article aims to present a comprehensive critical analysis of the current progress made in the area, including advantages, limitations, and future prospects for the practical application.",
keywords = "alkynes, gold catalysis, heterocycles, homogeneous catalysis, nitriles, oxazoles, oxidation",
author = "Дубовцев, {Алексей Юрьевич}",
year = "2025",
doi = "10.71267/mencom.7840",
language = "English",
volume = "35",
pages = "627–635",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - Gold-catalyzed O-transfer involving alkynes and nitriles as a straightforward diazo-free route to oxazoles

AU - Дубовцев, Алексей Юрьевич

PY - 2025

Y1 - 2025

N2 - In the recent years, the synthesis of oxazoles via (2 + 2 + 1) gold-catalyzed oxygen-transfer reactions involving alkynes and nitriles has become a dynamic field of study. The practical utility of this straightforward diazo-free method has been illustrated through a number of publications, among which are findings from our research group. This focus article aims to present a comprehensive critical analysis of the current progress made in the area, including advantages, limitations, and future prospects for the practical application.

AB - In the recent years, the synthesis of oxazoles via (2 + 2 + 1) gold-catalyzed oxygen-transfer reactions involving alkynes and nitriles has become a dynamic field of study. The practical utility of this straightforward diazo-free method has been illustrated through a number of publications, among which are findings from our research group. This focus article aims to present a comprehensive critical analysis of the current progress made in the area, including advantages, limitations, and future prospects for the practical application.

KW - alkynes

KW - gold catalysis

KW - heterocycles

KW - homogeneous catalysis

KW - nitriles

KW - oxazoles

KW - oxidation

UR - https://www.mendeley.com/catalogue/0317f3fb-0fe4-3331-a04b-d03c24b9c4b2/

U2 - 10.71267/mencom.7840

DO - 10.71267/mencom.7840

M3 - Literature review

VL - 35

SP - 627

EP - 635

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 6

ER -

ID: 142752331