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Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra. / Nazarchuk, Evgeny V.; Siidra, Oleg I.; Nekrasova, Diana O.; Shilovskikh, Vladimir V.; Borisov, Artem S.; Avdontseva, Evgeniya Y.

In: Mineralogical Magazine, Vol. 84, No. 4, 01.08.2020, p. 563-567.

Research output: Contribution to journal › Article › peer-review

Harvard

Nazarchuk, EV, Siidra, OI, Nekrasova, DO, Shilovskikh, VV, Borisov, AS & Avdontseva, EY 2020, 'Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra.', Mineralogical Magazine, vol. 84, no. 4, pp. 563-567. https://doi.org/10.1180/mgm.2020.33

APA

Nazarchuk, E. V., Siidra, O. I., Nekrasova, D. O., Shilovskikh, V. V., Borisov, A. S., & Avdontseva, E. Y. (2020). Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra. Mineralogical Magazine, 84(4), 563-567. https://doi.org/10.1180/mgm.2020.33

Vancouver

Nazarchuk EV, Siidra OI, Nekrasova DO, Shilovskikh VV, Borisov AS, Avdontseva EY. Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra. Mineralogical Magazine. 2020 Aug 1;84(4):563-567. https://doi.org/10.1180/mgm.2020.33

Author

Nazarchuk, Evgeny V. ; Siidra, Oleg I. ; Nekrasova, Diana O. ; Shilovskikh, Vladimir V. ; Borisov, Artem S. ; Avdontseva, Evgeniya Y. / Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra. In: Mineralogical Magazine. 2020 ; Vol. 84, No. 4. pp. 563-567.

BibTeX

@article{d60ef47c9d7c4654a1c74b7b1d463981,
title = "Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra.",
abstract = "A new mineral glikinite, ideally Zn3O(SO4)2, was found in higherature exhalative mineral assemblages in the Arsenatnaya fumarole, Second scoria cone of the Great Tolbachik Fissure Eruption (1975-1976), Tolbachik volcano, Kamchatka Peninsula, Russia. Glikinite is associated closely with langbeinite, lammerite-β, bradaczekite, euchlorine, anhydrite, chalcocyanite and tenorite. It is monoclinic, P21/m, a = 7.298(18), b = 6.588(11), c = 7.840(12) {\AA}, β = 117.15(3)°, V = 335.4(11) {\AA}3 and R1 = 0.046. The eight strongest lines of the powder X-ray diffraction pattern [d in {\AA} (I) (hkl)] are: 6.969(56)(00), 3.942(52)(101), 3.483(100)(00), 3.294(49)(020), 2.936(43)(120), 2.534(63)(201), 2.501(63)(20) and 2.395(86)(02). The chemical composition determined by electron-microprobe analysis is (wt.%): ZnO 42.47, CuO 19.50, SO3 39.96, total 101.93. The empirical formula calculated on the basis of O = 9 apfu is Zn2.07Cu0.97S1.98O9 and the simplified formula is Zn3O(SO4)2. Glikinite is a Zn,Cu analogue of synthetic Zn3O(SO4)2. The crystal structure of glikinite is based on OZn4 tetrahedra sharing common corners, thus forming [Zn3O]4+ chains. Sulfate groups interconnect [Zn3O]4+ chains into a 3D framework. ",
keywords = "framework structures, glikinite, new minerals, sulfates, Tolbachik volcano, zinc",
author = "Nazarchuk, {Evgeny V.} and Siidra, {Oleg I.} and Nekrasova, {Diana O.} and Shilovskikh, {Vladimir V.} and Borisov, {Artem S.} and Avdontseva, {Evgeniya Y.}",
note = "Funding Information: Supplementary material. To view supplementary material for this article, please visit https://doi.org/10.1180/mgm.2020.33 Acknowledgements. We are grateful to an anonymous reviewer, Ian Graham, Stuart Mills and Peter Leverett for valuable comments. This work was financially supported by the Russian Science Foundation, grant no. 16-17-10085. Technical support by the SPbSU X-ray Diffraction and Geomodel Resource Centres is gratefully acknowledged. Publisher Copyright: Copyright {\textcopyright} Mineralogical Society of Great Britain and Ireland 2020. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = aug,
day = "1",
doi = "10.1180/mgm.2020.33",
language = "English",
volume = "84",
pages = "563--567",
journal = "Mineralogical Magazine",
issn = "0026-461X",
publisher = "Mineralogical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4tetrahedra.

AU - Nazarchuk, Evgeny V.

AU - Siidra, Oleg I.

AU - Nekrasova, Diana O.

AU - Shilovskikh, Vladimir V.

AU - Borisov, Artem S.

AU - Avdontseva, Evgeniya Y.

N1 - Funding Information: Supplementary material. To view supplementary material for this article, please visit https://doi.org/10.1180/mgm.2020.33 Acknowledgements. We are grateful to an anonymous reviewer, Ian Graham, Stuart Mills and Peter Leverett for valuable comments. This work was financially supported by the Russian Science Foundation, grant no. 16-17-10085. Technical support by the SPbSU X-ray Diffraction and Geomodel Resource Centres is gratefully acknowledged. Publisher Copyright: Copyright © Mineralogical Society of Great Britain and Ireland 2020. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - A new mineral glikinite, ideally Zn3O(SO4)2, was found in higherature exhalative mineral assemblages in the Arsenatnaya fumarole, Second scoria cone of the Great Tolbachik Fissure Eruption (1975-1976), Tolbachik volcano, Kamchatka Peninsula, Russia. Glikinite is associated closely with langbeinite, lammerite-β, bradaczekite, euchlorine, anhydrite, chalcocyanite and tenorite. It is monoclinic, P21/m, a = 7.298(18), b = 6.588(11), c = 7.840(12) Å, β = 117.15(3)°, V = 335.4(11) Å3 and R1 = 0.046. The eight strongest lines of the powder X-ray diffraction pattern [d in Å (I) (hkl)] are: 6.969(56)(00), 3.942(52)(101), 3.483(100)(00), 3.294(49)(020), 2.936(43)(120), 2.534(63)(201), 2.501(63)(20) and 2.395(86)(02). The chemical composition determined by electron-microprobe analysis is (wt.%): ZnO 42.47, CuO 19.50, SO3 39.96, total 101.93. The empirical formula calculated on the basis of O = 9 apfu is Zn2.07Cu0.97S1.98O9 and the simplified formula is Zn3O(SO4)2. Glikinite is a Zn,Cu analogue of synthetic Zn3O(SO4)2. The crystal structure of glikinite is based on OZn4 tetrahedra sharing common corners, thus forming [Zn3O]4+ chains. Sulfate groups interconnect [Zn3O]4+ chains into a 3D framework.

AB - A new mineral glikinite, ideally Zn3O(SO4)2, was found in higherature exhalative mineral assemblages in the Arsenatnaya fumarole, Second scoria cone of the Great Tolbachik Fissure Eruption (1975-1976), Tolbachik volcano, Kamchatka Peninsula, Russia. Glikinite is associated closely with langbeinite, lammerite-β, bradaczekite, euchlorine, anhydrite, chalcocyanite and tenorite. It is monoclinic, P21/m, a = 7.298(18), b = 6.588(11), c = 7.840(12) Å, β = 117.15(3)°, V = 335.4(11) Å3 and R1 = 0.046. The eight strongest lines of the powder X-ray diffraction pattern [d in Å (I) (hkl)] are: 6.969(56)(00), 3.942(52)(101), 3.483(100)(00), 3.294(49)(020), 2.936(43)(120), 2.534(63)(201), 2.501(63)(20) and 2.395(86)(02). The chemical composition determined by electron-microprobe analysis is (wt.%): ZnO 42.47, CuO 19.50, SO3 39.96, total 101.93. The empirical formula calculated on the basis of O = 9 apfu is Zn2.07Cu0.97S1.98O9 and the simplified formula is Zn3O(SO4)2. Glikinite is a Zn,Cu analogue of synthetic Zn3O(SO4)2. The crystal structure of glikinite is based on OZn4 tetrahedra sharing common corners, thus forming [Zn3O]4+ chains. Sulfate groups interconnect [Zn3O]4+ chains into a 3D framework.

KW - framework structures

KW - glikinite

KW - new minerals

KW - sulfates

KW - Tolbachik volcano

KW - zinc

UR - http://www.scopus.com/inward/record.url?scp=85091431214&partnerID=8YFLogxK

U2 - 10.1180/mgm.2020.33

DO - 10.1180/mgm.2020.33

M3 - Article

AN - SCOPUS:85091431214

VL - 84

SP - 563

EP - 567

JO - Mineralogical Magazine

JF - Mineralogical Magazine

SN - 0026-461X

IS - 4

ER -

ID: 74784740