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Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data. / Levin, A.A.; Meyer, D.C.; Filatov, S.K.; Georgievskaya, M.I.; Paufler, P.; Bubnova, R.S.; Ugolkov, V.L.

In: Zeitschrift fur Kristallographie, Vol. 227, No. 7, 2012, p. 494-501.

Research output: Contribution to journal › Article

Harvard

Levin, AA, Meyer, DC, Filatov, SK, Georgievskaya, MI, Paufler, P, Bubnova, RS & Ugolkov, VL 2012, 'Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data', Zeitschrift fur Kristallographie, vol. 227, no. 7, pp. 494-501. <http://www.oldenbourg-link.com/doi/abs/10.1524/zkri.2012.1458>

APA

Levin, A. A., Meyer, D. C., Filatov, S. K., Georgievskaya, M. I., Paufler, P., Bubnova, R. S., & Ugolkov, V. L. (2012). Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data. Zeitschrift fur Kristallographie, 227(7), 494-501. http://www.oldenbourg-link.com/doi/abs/10.1524/zkri.2012.1458

Vancouver

Levin AA, Meyer DC, Filatov SK, Georgievskaya MI, Paufler P, Bubnova RS et al. Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data. Zeitschrift fur Kristallographie. 2012;227(7):494-501.

Author

Levin, A.A. ; Meyer, D.C. ; Filatov, S.K. ; Georgievskaya, M.I. ; Paufler, P. ; Bubnova, R.S. ; Ugolkov, V.L. / Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data. In: Zeitschrift fur Kristallographie. 2012 ; Vol. 227, No. 7. pp. 494-501.

BibTeX

@article{b2cbf8f5bba04fd58fba639f520f2dce,
title = "Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data",
abstract = "For technologically important borosilicate glass and crystalline phases, the structure of K1−xRbxBSi2O6 (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) solid solutions has been investigated employing X-ray diffraction data. Glass samples were prepared by a melt quenching from 1250–1300 °C for 0.5–1 hour. For glass samples glass transition(Tg), crystallization (Tcryst) and melting (Tm) temperatures were determined by differential scanning calorimetry. To investigate the glass structure, angle-dispersive X-ray diffractometry was applied by using an energy-resolving semiconductor detector. The radial distribution functions (RDFs) were calculated. Comparing correlation distances of glass RDFs and mean interatomic distances calculated for polycrystalline samples, the conclusion is drawn that in the glass state not only TO4 (T = Si, B) tetrahedra as stable structure-units but two corner sharing tetrahedra and apparently fourfold rings from tetrahedra exist. Read More: http://www.oldenbourg-link.com/doi/abs/10.1524/zkri.2012.1",
keywords = "Borosilicate, Glass structure, Thermal behaviour",
author = "A.A. Levin and D.C. Meyer and S.K. Filatov and M.I. Georgievskaya and P. Paufler and R.S. Bubnova and V.L. Ugolkov",
year = "2012",
language = "English",
volume = "227",
pages = "494--501",
journal = "Zeitschfrift fur Kristallographie",
issn = "0044-2968",
publisher = "De Gruyter",
number = "7",

}

RIS

TY - JOUR

T1 - Glass structural studies for borosilicates of the KBSi2O6-RbBSi2O6 system from X-ray diffraction data

AU - Levin, A.A.

AU - Meyer, D.C.

AU - Filatov, S.K.

AU - Georgievskaya, M.I.

AU - Paufler, P.

AU - Bubnova, R.S.

AU - Ugolkov, V.L.

PY - 2012

Y1 - 2012

N2 - For technologically important borosilicate glass and crystalline phases, the structure of K1−xRbxBSi2O6 (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) solid solutions has been investigated employing X-ray diffraction data. Glass samples were prepared by a melt quenching from 1250–1300 °C for 0.5–1 hour. For glass samples glass transition(Tg), crystallization (Tcryst) and melting (Tm) temperatures were determined by differential scanning calorimetry. To investigate the glass structure, angle-dispersive X-ray diffractometry was applied by using an energy-resolving semiconductor detector. The radial distribution functions (RDFs) were calculated. Comparing correlation distances of glass RDFs and mean interatomic distances calculated for polycrystalline samples, the conclusion is drawn that in the glass state not only TO4 (T = Si, B) tetrahedra as stable structure-units but two corner sharing tetrahedra and apparently fourfold rings from tetrahedra exist. Read More: http://www.oldenbourg-link.com/doi/abs/10.1524/zkri.2012.1

AB - For technologically important borosilicate glass and crystalline phases, the structure of K1−xRbxBSi2O6 (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) solid solutions has been investigated employing X-ray diffraction data. Glass samples were prepared by a melt quenching from 1250–1300 °C for 0.5–1 hour. For glass samples glass transition(Tg), crystallization (Tcryst) and melting (Tm) temperatures were determined by differential scanning calorimetry. To investigate the glass structure, angle-dispersive X-ray diffractometry was applied by using an energy-resolving semiconductor detector. The radial distribution functions (RDFs) were calculated. Comparing correlation distances of glass RDFs and mean interatomic distances calculated for polycrystalline samples, the conclusion is drawn that in the glass state not only TO4 (T = Si, B) tetrahedra as stable structure-units but two corner sharing tetrahedra and apparently fourfold rings from tetrahedra exist. Read More: http://www.oldenbourg-link.com/doi/abs/10.1524/zkri.2012.1

KW - Borosilicate

KW - Glass structure

KW - Thermal behaviour

M3 - Article

VL - 227

SP - 494

EP - 501

JO - Zeitschfrift fur Kristallographie

JF - Zeitschfrift fur Kristallographie

SN - 0044-2968

IS - 7

ER -

ID: 5343014