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Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors : structural, thermal, and electrical properties. / Murashkina, A. A.; Pikalova, E. Yu; Medvedev, D. A.

In: Ionics, Vol. 23, No. 9, 01.09.2017, p. 2351-2357.

Research output: Contribution to journal › Article › peer-review

Harvard

Murashkina, AA, Pikalova, EY & Medvedev, DA 2017, 'Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors: structural, thermal, and electrical properties', Ionics, vol. 23, no. 9, pp. 2351-2357. https://doi.org/10.1007/s11581-017-2075-0

APA

Murashkina, A. A., Pikalova, E. Y., & Medvedev, D. A. (2017). Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors: structural, thermal, and electrical properties. Ionics, 23(9), 2351-2357. https://doi.org/10.1007/s11581-017-2075-0

Vancouver

Murashkina AA, Pikalova EY, Medvedev DA. Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors: structural, thermal, and electrical properties. Ionics. 2017 Sep 1;23(9):2351-2357. https://doi.org/10.1007/s11581-017-2075-0

Author

Murashkina, A. A. ; Pikalova, E. Yu ; Medvedev, D. A. / Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors : structural, thermal, and electrical properties. In: Ionics. 2017 ; Vol. 23, No. 9. pp. 2351-2357.

BibTeX

@article{d4cb3535ae2540c0ba85b84a2fe5eb16,
title = "Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors: structural, thermal, and electrical properties",
abstract = "The effect of Sr by Gd substitution on the structural, thermomechanical, electrical, and electrochemical properties of SrTi0.5Fe0.5O3–δ was investigated in the present work. The powders were synthesized by a solid-state reaction method at 1150 °C with following sintering of the ceramic samples at 1350 °C. The unit cell parameters of the sintered Sr1–xGdxTi0.5Fe0.5O3–δ (x = 0–0.4) ceramics were found to decrease with a gradual increase in Gd content, and a change in the crystal symmetry from cubic to tetragonal at x ≥ 0.1 was observed. It was found that the Gd doping enhanced the stability of the ceramic samples in a reducing atmosphere and reduced the thermal expansion coefficient value. Gd doping in the amount of 5 mol% can be used for long-term stabilization of the SrTi0.5Fe0.5O3–δ material{\textquoteright}s conductivity in reducing atmospheres with no significant alteration to the transport properties and oxygen permeability.",
keywords = "Ionic conductivity, MIECs, Oxygen permeability, SrTiO, TEC",
author = "Murashkina, {A. A.} and Pikalova, {E. Yu} and Medvedev, {D. A.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1007/s11581-017-2075-0",
language = "English",
volume = "23",
pages = "2351--2357",
journal = "Ionics",
issn = "0947-7047",
publisher = "Institute for Ionics",
number = "9",

}

RIS

TY - JOUR

T1 - Gd-doped SrTi0.5Fe0.5O3–δ mixed ionic-electronic conductors

T2 - structural, thermal, and electrical properties

AU - Murashkina, A. A.

AU - Pikalova, E. Yu

AU - Medvedev, D. A.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - The effect of Sr by Gd substitution on the structural, thermomechanical, electrical, and electrochemical properties of SrTi0.5Fe0.5O3–δ was investigated in the present work. The powders were synthesized by a solid-state reaction method at 1150 °C with following sintering of the ceramic samples at 1350 °C. The unit cell parameters of the sintered Sr1–xGdxTi0.5Fe0.5O3–δ (x = 0–0.4) ceramics were found to decrease with a gradual increase in Gd content, and a change in the crystal symmetry from cubic to tetragonal at x ≥ 0.1 was observed. It was found that the Gd doping enhanced the stability of the ceramic samples in a reducing atmosphere and reduced the thermal expansion coefficient value. Gd doping in the amount of 5 mol% can be used for long-term stabilization of the SrTi0.5Fe0.5O3–δ material’s conductivity in reducing atmospheres with no significant alteration to the transport properties and oxygen permeability.

AB - The effect of Sr by Gd substitution on the structural, thermomechanical, electrical, and electrochemical properties of SrTi0.5Fe0.5O3–δ was investigated in the present work. The powders were synthesized by a solid-state reaction method at 1150 °C with following sintering of the ceramic samples at 1350 °C. The unit cell parameters of the sintered Sr1–xGdxTi0.5Fe0.5O3–δ (x = 0–0.4) ceramics were found to decrease with a gradual increase in Gd content, and a change in the crystal symmetry from cubic to tetragonal at x ≥ 0.1 was observed. It was found that the Gd doping enhanced the stability of the ceramic samples in a reducing atmosphere and reduced the thermal expansion coefficient value. Gd doping in the amount of 5 mol% can be used for long-term stabilization of the SrTi0.5Fe0.5O3–δ material’s conductivity in reducing atmospheres with no significant alteration to the transport properties and oxygen permeability.

KW - Ionic conductivity

KW - MIECs

KW - Oxygen permeability

KW - SrTiO

KW - TEC

UR - http://www.scopus.com/inward/record.url?scp=85016092376&partnerID=8YFLogxK

U2 - 10.1007/s11581-017-2075-0

DO - 10.1007/s11581-017-2075-0

M3 - Article

AN - SCOPUS:85016092376

VL - 23

SP - 2351

EP - 2357

JO - Ionics

JF - Ionics

SN - 0947-7047

IS - 9

ER -

ID: 9706582