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Gas phase association reactions in 13-15 CVD : Annoying obstacle or rewarding advantage? / Timoshkin, Alexey Y.

EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition. ed. / A. Devi; R. Fischer; H. Parala; M.D. Allendorf; M. Hitchman. Vol. PV 2005-09 2005. p. 87-94.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

Harvard

Timoshkin, AY 2005, Gas phase association reactions in 13-15 CVD: Annoying obstacle or rewarding advantage? in A Devi, R Fischer, H Parala, MD Allendorf & M Hitchman (eds), EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition. vol. PV 2005-09, pp. 87-94, 15th European Conference on Chemical Vapor Deposition, EUROCVD-15, Bochum, Germany, 5/09/05.

APA

Timoshkin, A. Y. (2005). Gas phase association reactions in 13-15 CVD: Annoying obstacle or rewarding advantage? In A. Devi, R. Fischer, H. Parala, M. D. Allendorf, & M. Hitchman (Eds.), EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition (Vol. PV 2005-09, pp. 87-94)

Vancouver

Timoshkin AY. Gas phase association reactions in 13-15 CVD: Annoying obstacle or rewarding advantage? In Devi A, Fischer R, Parala H, Allendorf MD, Hitchman M, editors, EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition. Vol. PV 2005-09. 2005. p. 87-94

Author

Timoshkin, Alexey Y. / Gas phase association reactions in 13-15 CVD : Annoying obstacle or rewarding advantage?. EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition. editor / A. Devi ; R. Fischer ; H. Parala ; M.D. Allendorf ; M. Hitchman. Vol. PV 2005-09 2005. pp. 87-94

BibTeX

@inproceedings{377e44583cb14555b90b6152e8c64f70,
title = "Gas phase association reactions in 13-15 CVD: Annoying obstacle or rewarding advantage?",
abstract = "Chemistry of gas phase association reactions in 13-15 CVD has been reviewed. Results of the extensive quantum chemical modeling of group 13-15 CVD show high thermodynamic favorability of the association reactions even at elevated (700-1000 K) temperatures. Formation of a variety of ring, cage and cluster species is viable in vapors; among them the needle-shaped oligomers and polymers are predicted to have an exceptional stability. Thus, generation of 13-15 nanowires and nanoparticles via association route emerges as a viable alternative to the traditional surface-based CVD techniques. Competitiveness of the metal - pnictogen and metal - carbon bonds results in carbon inclusion into the cluster core with formation of the 13-15-carbon cages, which are expected to be kinetically stable. This may limit the practical use of the association reactions starting from the metallorganic precursors. Formation of the nitrogen-rich adamantine-like cages is viable in the excess of ammonia at temperatures below 700K.",
author = "Timoshkin, {Alexey Y.}",
year = "2005",
language = "English",
volume = "PV 2005-09",
pages = "87--94",
editor = "A. Devi and R. Fischer and H. Parala and M.D. Allendorf and M. Hitchman",
booktitle = "EUROCVD-15",
note = "15th European Conference on Chemical Vapor Deposition, EUROCVD-15 ; Conference date: 05-09-2005 Through 09-09-2005",

}

RIS

TY - GEN

T1 - Gas phase association reactions in 13-15 CVD

T2 - 15th European Conference on Chemical Vapor Deposition, EUROCVD-15

AU - Timoshkin, Alexey Y.

PY - 2005

Y1 - 2005

N2 - Chemistry of gas phase association reactions in 13-15 CVD has been reviewed. Results of the extensive quantum chemical modeling of group 13-15 CVD show high thermodynamic favorability of the association reactions even at elevated (700-1000 K) temperatures. Formation of a variety of ring, cage and cluster species is viable in vapors; among them the needle-shaped oligomers and polymers are predicted to have an exceptional stability. Thus, generation of 13-15 nanowires and nanoparticles via association route emerges as a viable alternative to the traditional surface-based CVD techniques. Competitiveness of the metal - pnictogen and metal - carbon bonds results in carbon inclusion into the cluster core with formation of the 13-15-carbon cages, which are expected to be kinetically stable. This may limit the practical use of the association reactions starting from the metallorganic precursors. Formation of the nitrogen-rich adamantine-like cages is viable in the excess of ammonia at temperatures below 700K.

AB - Chemistry of gas phase association reactions in 13-15 CVD has been reviewed. Results of the extensive quantum chemical modeling of group 13-15 CVD show high thermodynamic favorability of the association reactions even at elevated (700-1000 K) temperatures. Formation of a variety of ring, cage and cluster species is viable in vapors; among them the needle-shaped oligomers and polymers are predicted to have an exceptional stability. Thus, generation of 13-15 nanowires and nanoparticles via association route emerges as a viable alternative to the traditional surface-based CVD techniques. Competitiveness of the metal - pnictogen and metal - carbon bonds results in carbon inclusion into the cluster core with formation of the 13-15-carbon cages, which are expected to be kinetically stable. This may limit the practical use of the association reactions starting from the metallorganic precursors. Formation of the nitrogen-rich adamantine-like cages is viable in the excess of ammonia at temperatures below 700K.

UR - http://www.scopus.com/inward/record.url?scp=31844439412&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:31844439412

VL - PV 2005-09

SP - 87

EP - 94

BT - EUROCVD-15

A2 - Devi, A.

A2 - Fischer, R.

A2 - Parala, H.

A2 - Allendorf, M.D.

A2 - Hitchman, M.

Y2 - 5 September 2005 through 9 September 2005

ER -

ID: 17372961