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Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class. / Voinova, Vera V.; Selivanov, Nikita A.; Plyushchenko, Ivan V.; Vokuev, Mikhail F.; Bykov, Alexander Yu; Klyukin, Ilya N.; Novikov, Alexander S.; Zhdanov, Andrey P.; Grigoriev, Mikhail S.; Rodin, Igor A.; Zhizhin, Konstantin Yu; Kuznetsov, Nikolay T.

In: Molecules (Basel, Switzerland), Vol. 26, No. 1, 248, 05.01.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Voinova, VV, Selivanov, NA, Plyushchenko, IV, Vokuev, MF, Bykov, AY, Klyukin, IN, Novikov, AS, Zhdanov, AP, Grigoriev, MS, Rodin, IA, Zhizhin, KY & Kuznetsov, NT 2021, 'Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class', Molecules (Basel, Switzerland), vol. 26, no. 1, 248. https://doi.org/10.3390/molecules26010248

APA

Voinova, V. V., Selivanov, N. A., Plyushchenko, I. V., Vokuev, M. F., Bykov, A. Y., Klyukin, I. N., Novikov, A. S., Zhdanov, A. P., Grigoriev, M. S., Rodin, I. A., Zhizhin, K. Y., & Kuznetsov, N. T. (2021). Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class. Molecules (Basel, Switzerland), 26(1), [248]. https://doi.org/10.3390/molecules26010248

Vancouver

Voinova VV, Selivanov NA, Plyushchenko IV, Vokuev MF, Bykov AY, Klyukin IN et al. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class. Molecules (Basel, Switzerland). 2021 Jan 5;26(1). 248. https://doi.org/10.3390/molecules26010248

Author

Voinova, Vera V. ; Selivanov, Nikita A. ; Plyushchenko, Ivan V. ; Vokuev, Mikhail F. ; Bykov, Alexander Yu ; Klyukin, Ilya N. ; Novikov, Alexander S. ; Zhdanov, Andrey P. ; Grigoriev, Mikhail S. ; Rodin, Igor A. ; Zhizhin, Konstantin Yu ; Kuznetsov, Nikolay T. / Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class. In: Molecules (Basel, Switzerland). 2021 ; Vol. 26, No. 1.

BibTeX

@article{b7314532e08d4f8db0c27c1e99acc178,
title = "Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class",
abstract = "The novel members of the 1,2-diboraoxazoles family have been obtained. In the present work, we have carried out the intramolecular ring-closure reaction of borylated iminols of general type [B10H9N=C(OH)R]- (R = Me, Et, nPr, iPr, tBu, Ph, 4-Cl-Ph). This process is conducted in mild conditions with 83-87% yields. The solid-state structures of two salts of 1,2-diboraoxazoles were additionally investigated by X-ray crystallography. In addition, the phenomena of bonding interactions in the 1,2-diboraoxazole cycles have been theoretically studied by the Quantum Theory of Atoms in Molecules analysis. Several local and integral topological properties of the electron density involved in these interactions have been computed.",
keywords = "closo-decaborate, diboraoxazole, iminol, intramolecular ring-closure reaction, QTAIM analysis, ASTATINATION, REAGENTS, MECHANISM, COMPLEXES, CARBORANE, CLUSTER, B-H, DERIVATIVES",
author = "Voinova, {Vera V.} and Selivanov, {Nikita A.} and Plyushchenko, {Ivan V.} and Vokuev, {Mikhail F.} and Bykov, {Alexander Yu} and Klyukin, {Ilya N.} and Novikov, {Alexander S.} and Zhdanov, {Andrey P.} and Grigoriev, {Mikhail S.} and Rodin, {Igor A.} and Zhizhin, {Konstantin Yu} and Kuznetsov, {Nikolay T.}",
note = "Copyright: This record is sourced from MEDLINE/PubMed, a database of the U.S. National Library of Medicine",
year = "2021",
month = jan,
day = "5",
doi = "10.3390/molecules26010248",
language = "English",
volume = "26",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "1",

}

RIS

TY - JOUR

T1 - Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class

AU - Voinova, Vera V.

AU - Selivanov, Nikita A.

AU - Plyushchenko, Ivan V.

AU - Vokuev, Mikhail F.

AU - Bykov, Alexander Yu

AU - Klyukin, Ilya N.

AU - Novikov, Alexander S.

AU - Zhdanov, Andrey P.

AU - Grigoriev, Mikhail S.

AU - Rodin, Igor A.

AU - Zhizhin, Konstantin Yu

AU - Kuznetsov, Nikolay T.

N1 - Copyright: This record is sourced from MEDLINE/PubMed, a database of the U.S. National Library of Medicine

PY - 2021/1/5

Y1 - 2021/1/5

N2 - The novel members of the 1,2-diboraoxazoles family have been obtained. In the present work, we have carried out the intramolecular ring-closure reaction of borylated iminols of general type [B10H9N=C(OH)R]- (R = Me, Et, nPr, iPr, tBu, Ph, 4-Cl-Ph). This process is conducted in mild conditions with 83-87% yields. The solid-state structures of two salts of 1,2-diboraoxazoles were additionally investigated by X-ray crystallography. In addition, the phenomena of bonding interactions in the 1,2-diboraoxazole cycles have been theoretically studied by the Quantum Theory of Atoms in Molecules analysis. Several local and integral topological properties of the electron density involved in these interactions have been computed.

AB - The novel members of the 1,2-diboraoxazoles family have been obtained. In the present work, we have carried out the intramolecular ring-closure reaction of borylated iminols of general type [B10H9N=C(OH)R]- (R = Me, Et, nPr, iPr, tBu, Ph, 4-Cl-Ph). This process is conducted in mild conditions with 83-87% yields. The solid-state structures of two salts of 1,2-diboraoxazoles were additionally investigated by X-ray crystallography. In addition, the phenomena of bonding interactions in the 1,2-diboraoxazole cycles have been theoretically studied by the Quantum Theory of Atoms in Molecules analysis. Several local and integral topological properties of the electron density involved in these interactions have been computed.

KW - closo-decaborate

KW - diboraoxazole

KW - iminol

KW - intramolecular ring-closure reaction

KW - QTAIM analysis

KW - ASTATINATION

KW - REAGENTS

KW - MECHANISM

KW - COMPLEXES

KW - CARBORANE

KW - CLUSTER

KW - B-H

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85100325051&partnerID=8YFLogxK

U2 - 10.3390/molecules26010248

DO - 10.3390/molecules26010248

M3 - Article

C2 - 33466558

AN - SCOPUS:85100325051

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 1

M1 - 248

ER -

ID: 73921877