Research output: Contribution to journal › Article › peer-review
FTIR spectroscopy evidence for the basicity induced by adsorption. / Storozheva, E. N.; Sekushin, V. N.; Tsyganenko, A. A.
In: Catalysis Letters, Vol. 107, No. 3-4, 03.2006, p. 185-188.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - FTIR spectroscopy evidence for the basicity induced by adsorption
AU - Storozheva, E. N.
AU - Sekushin, V. N.
AU - Tsyganenko, A. A.
PY - 2006/3
Y1 - 2006/3
N2 - Basicity of silanol oxygen atom increases after adsorption of ammonia or pyridine, as revealed by FTIR spectra of adsorbed CHF3 and CO 2. The same effect of "induced basicity" was observed for the dangling hydroxyl groups of ice surface with coadsorbed ethylene and fluoroform. Possible role of the induced acidity and basicity in surface chemistry is discussed.
AB - Basicity of silanol oxygen atom increases after adsorption of ammonia or pyridine, as revealed by FTIR spectra of adsorbed CHF3 and CO 2. The same effect of "induced basicity" was observed for the dangling hydroxyl groups of ice surface with coadsorbed ethylene and fluoroform. Possible role of the induced acidity and basicity in surface chemistry is discussed.
KW - Adsorption
KW - Basicity
KW - Fluoroform
KW - FTIR spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=33645083478&partnerID=8YFLogxK
U2 - 10.1007/s10562-005-0008-4
DO - 10.1007/s10562-005-0008-4
M3 - Article
AN - SCOPUS:33645083478
VL - 107
SP - 185
EP - 188
JO - Catalysis Letters
JF - Catalysis Letters
SN - 1011-372X
IS - 3-4
ER -
ID: 13733468