Research output: Contribution to journal › Article › peer-review
From Rare Reagents to Rare Products : Regiospecific Silver-Catalyzed [3+2] Cycloaddition of Aryl-, Alkyl- and Aminosulfonyl Diazomethanes with Arenediazonium Tosylates. / Levashova, Ekaterina; Bakulina, Olga; Dar'in, Dmitry; Bubyrev, Andrey; Chuprun, Sergey; Krasavin, Mikhail.
In: European Journal of Organic Chemistry, Vol. 2020, No. 27, 23.07.2020, p. 4239-4242.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - From Rare Reagents to Rare Products
T2 - Regiospecific Silver-Catalyzed [3+2] Cycloaddition of Aryl-, Alkyl- and Aminosulfonyl Diazomethanes with Arenediazonium Tosylates
AU - Levashova, Ekaterina
AU - Bakulina, Olga
AU - Dar'in, Dmitry
AU - Bubyrev, Andrey
AU - Chuprun, Sergey
AU - Krasavin, Mikhail
N1 - Funding Information: This research was supported by the Russian Foundation for Basic Research (project grant 18-33-20194). We thank the Research Centre for Magnetic Resonance and the Center for Chemical Analysis and Materials Research of Saint Petersburg State University Research Park for obtaining the analytical data. Publisher Copyright: © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2020/7/23
Y1 - 2020/7/23
N2 - The scope of silver nitrate-catalyzed cycloaddition of arenediazonium salts has been expanded to include aryl- and alkylsulfonyl diazomethanes as well as the recently introduced diazomethyl sulfonamides. The reliance on these two classes of diazo compounds led to a new synthetic approach to the rare 2-aryltetrazol-5-yl sulfones as well as to the synthesis of hitherto not described 2-aryltetrazol-5-yl sulfonamides.
AB - The scope of silver nitrate-catalyzed cycloaddition of arenediazonium salts has been expanded to include aryl- and alkylsulfonyl diazomethanes as well as the recently introduced diazomethyl sulfonamides. The reliance on these two classes of diazo compounds led to a new synthetic approach to the rare 2-aryltetrazol-5-yl sulfones as well as to the synthesis of hitherto not described 2-aryltetrazol-5-yl sulfonamides.
KW - Cycloaddition
KW - Diazo compounds
KW - Homogeneous catalysis
KW - Silver
KW - Synthetic methods
KW - Tetrazoles
KW - IN-SITU GENERATION
KW - MEDICINAL CHEMISTRY
KW - DIAZOSULFONES
KW - TETRAZOLES
KW - SALTS
KW - MILD
UR - http://www.scopus.com/inward/record.url?scp=85087635311&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/fcf3fda8-3171-3ae0-93d7-a1f8be27fe2b/
U2 - 10.1002/ejoc.202000619
DO - 10.1002/ejoc.202000619
M3 - статья
VL - 2020
SP - 4239
EP - 4242
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1434-193X
IS - 27
ER -
ID: 60767897