From comb-like polyelectrolytes to polyelectrolyte-surfactant complexes: Effect of the length of the aliphatic tail of the counterions on self-organization in solid state

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From comb-like polyelectrolytes to polyelectrolyte-surfactant complexes: Effect of the length of the aliphatic tail of the counterions on self-organization in solid state. / Фетин, Петр Александрович; Бревнов, Олег Николаевич; Кадников, Матвей Викторинович; Фетина, Вероника Ивановна; Билибин, Александр Юрьевич ; Зорин, Иван Михайлович.

In: European Polymer Journal, Vol. 152, 110468, 05.06.2021.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{65c12bf24a9b40f4a381ce0e69f3e6d5,

title = "From comb-like polyelectrolytes to polyelectrolyte-surfactant complexes: Effect of the length of the aliphatic tail of the counterions on self-organization in solid state",

abstract = "Cationic comb-like polyelectrolyte poly(11-acryloyloxyundecyltrimethylammonium) with acidic residues of acetic, butanoic, hexanoic, octanoic, decanoic, dodecanoic acids as counterions were synthesized. Those polyelectrolyte series on increasing of counterion tail length demonstrate the smooth transition from typical comb-like polyelectrolytes to polyelectrolyte-surfactant complexes. All complexes are water soluble, and dissociate in aqueous NaCl. Increasing of counterion hydrophobicity results transformation from hexagonal packing (acetic and butanoic counterions) to amorphous phase (hexanoic counterions) and then to lamellar packing (octanoic, decanoic and dodecanoic counterions) of solid complexes. The formed structures are stable up to 150 °C and decompose with destruction of chemical structure.",

keywords = "Comb-like polyelectrolytes, Ordered polymer structure, Polyelectrolyte complex, Self-assembly, small-angle X-rays diffraction, INTERPOLYELECTROLYTE, POLYMERIZED MICELLES, ASSEMBLED POLYELECTROLYTE",

author = "Фетин, {Петр Александрович} and Бревнов, {Олег Николаевич} and Кадников, {Матвей Викторинович} and Фетина, {Вероника Ивановна} and Билибин, {Александр Юрьевич} and Зорин, {Иван Михайлович}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = jun,

day = "5",

doi = "10.1016/j.eurpolymj.2021.110468",

language = "English",

volume = "152",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - From comb-like polyelectrolytes to polyelectrolyte-surfactant complexes: Effect of the length of the aliphatic tail of the counterions on self-organization in solid state

AU - Фетин, Петр Александрович

AU - Бревнов, Олег Николаевич

AU - Кадников, Матвей Викторинович

AU - Фетина, Вероника Ивановна

AU - Билибин, Александр Юрьевич

AU - Зорин, Иван Михайлович

PY - 2021/6/5

Y1 - 2021/6/5

N2 - Cationic comb-like polyelectrolyte poly(11-acryloyloxyundecyltrimethylammonium) with acidic residues of acetic, butanoic, hexanoic, octanoic, decanoic, dodecanoic acids as counterions were synthesized. Those polyelectrolyte series on increasing of counterion tail length demonstrate the smooth transition from typical comb-like polyelectrolytes to polyelectrolyte-surfactant complexes. All complexes are water soluble, and dissociate in aqueous NaCl. Increasing of counterion hydrophobicity results transformation from hexagonal packing (acetic and butanoic counterions) to amorphous phase (hexanoic counterions) and then to lamellar packing (octanoic, decanoic and dodecanoic counterions) of solid complexes. The formed structures are stable up to 150 °C and decompose with destruction of chemical structure.

AB - Cationic comb-like polyelectrolyte poly(11-acryloyloxyundecyltrimethylammonium) with acidic residues of acetic, butanoic, hexanoic, octanoic, decanoic, dodecanoic acids as counterions were synthesized. Those polyelectrolyte series on increasing of counterion tail length demonstrate the smooth transition from typical comb-like polyelectrolytes to polyelectrolyte-surfactant complexes. All complexes are water soluble, and dissociate in aqueous NaCl. Increasing of counterion hydrophobicity results transformation from hexagonal packing (acetic and butanoic counterions) to amorphous phase (hexanoic counterions) and then to lamellar packing (octanoic, decanoic and dodecanoic counterions) of solid complexes. The formed structures are stable up to 150 °C and decompose with destruction of chemical structure.

KW - Comb-like polyelectrolytes

KW - Ordered polymer structure

KW - Polyelectrolyte complex

KW - Self-assembly

KW - small-angle X-rays diffraction

KW - INTERPOLYELECTROLYTE

KW - POLYMERIZED MICELLES

KW - ASSEMBLED POLYELECTROLYTE

UR - http://www.scopus.com/inward/record.url?scp=85105037881&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/8678fe04-42c0-3edf-a4fe-bcb43fc7a64c/

U2 - 10.1016/j.eurpolymj.2021.110468

DO - 10.1016/j.eurpolymj.2021.110468

M3 - Article

VL - 152

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

M1 - 110468

ER -

ID: 76770431