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Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers. / Shamsieva, Aliia V.; Kolesnikov, Ilya E.; Strelnik, Igor D.; Gerasimova, Tatiana P.; Kalinichev, Alexey A.; Katsyuba, Sergey A.; Musina, Elvira I.; Lähderanta, Erkki; Karasik, Andrey A.; Sinyashin, Oleg G.
In:
Journal of Physical Chemistry C, Vol. 123, No. 42, 24.10.2019, p. 25863-25870.
Research output: Contribution to journal › Article › peer-review
Harvard
Shamsieva, AV, Kolesnikov, IE, Strelnik, ID, Gerasimova, TP, Kalinichev, AA, Katsyuba, SA, Musina, EI, Lähderanta, E, Karasik, AA & Sinyashin, OG 2019, '
Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers',
Journal of Physical Chemistry C, vol. 123, no. 42, pp. 25863-25870.
https://doi.org/10.1021/acs.jpcc.9b07603APA
Shamsieva, A. V., Kolesnikov, I. E., Strelnik, I. D., Gerasimova, T. P., Kalinichev, A. A., Katsyuba, S. A., Musina, E. I., Lähderanta, E., Karasik, A. A., & Sinyashin, O. G. (2019).
Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers.
Journal of Physical Chemistry C,
123(42), 25863-25870.
https://doi.org/10.1021/acs.jpcc.9b07603Vancouver
Author
Shamsieva, Aliia V. ; Kolesnikov, Ilya E. ; Strelnik, Igor D. ; Gerasimova, Tatiana P. ; Kalinichev, Alexey A. ; Katsyuba, Sergey A. ; Musina, Elvira I. ; Lähderanta, Erkki ; Karasik, Andrey A. ; Sinyashin, Oleg G. /
Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers. In:
Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 42. pp. 25863-25870.
BibTeX
@article{42f59657fec34b3e94c9ae64ae57c558,
title = "Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers",
abstract = "For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.",
author = "Shamsieva, {Aliia V.} and Kolesnikov, {Ilya E.} and Strelnik, {Igor D.} and Gerasimova, {Tatiana P.} and Kalinichev, {Alexey A.} and Katsyuba, {Sergey A.} and Musina, {Elvira I.} and Erkki L{\"a}hderanta and Karasik, {Andrey A.} and Sinyashin, {Oleg G.}",
year = "2019",
month = oct,
day = "24",
doi = "10.1021/acs.jpcc.9b07603",
language = "English",
volume = "123",
pages = "25863--25870",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "42",
}
RIS
TY - JOUR
T1 - Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters-Promising Ratiometric Luminescent Thermometers
AU - Shamsieva, Aliia V.
AU - Kolesnikov, Ilya E.
AU - Strelnik, Igor D.
AU - Gerasimova, Tatiana P.
AU - Kalinichev, Alexey A.
AU - Katsyuba, Sergey A.
AU - Musina, Elvira I.
AU - Lähderanta, Erkki
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
PY - 2019/10/24
Y1 - 2019/10/24
N2 - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
AB - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
UR - http://www.scopus.com/inward/record.url?scp=85073366699&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.9b07603
DO - 10.1021/acs.jpcc.9b07603
M3 - Article
AN - SCOPUS:85073366699
VL - 123
SP - 25863
EP - 25870
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 42
ER -
