TY - JOUR

T1 - Framework Uranyl Silicates: Crystal Chemistry and a New Route for the Synthesis

AU - Назарчук, Евгений Васильевич

AU - Сийдра, Олег Иоханнесович

AU - Чаркин, Дмитрий

AU - Тагирова, Яна Галиевна

PY - 2023/6/2

Y1 - 2023/6/2

N2 - To date, uranyl silicates are mostly represented by minerals in nature. However, their synthetic counterparts can be used as ion exchange materials. A new approach for the synthesis of framework uranyl silicates is reported. The new compounds Rb 2[(UO 2) 2(Si 8O 19)](H 2O) 2.5 ( 1), (K,Rb) 2[(UO 2)(Si 10O 22)] ( 2), [Rb 3Cl][(UO 2)(Si 4O 10)] ( 3) and [Cs 3Cl][(UO 2)(Si 4O 10)] ( 4) were prepared at harsh conditions in "activated" silica tubes at 900 °C. The activation of silica was performed using 40% hydrofluoric acid and lead oxide. Crystal structures of new uranyl silicates were solved by direct methods and refined: 1 is orthorhombic, Cmce, a = 14.5795(2) Å, b = 14.2083(2) Å, c = 23.1412(4) Å, V = 4793.70(13) Å 3, R1 = 0.023; 2 is monoclinic, C2/ m, a = 23.0027(8) Å, b = 8.0983(3) Å, c = 11.9736(4) Å, β = 90.372(3) °, V = 2230.43(14) Å 3, R1 = 0.034; 3 is orthorhombic, Imma, a = 15.2712(12) Å, b = 7.9647(8) Å, c = 12.4607(9) Å, V = 1515.6(2) Å 3, R1 = 0.035, 4 is orthorhombic, Imma, a = 15.4148(8) Å, b = 7.9229(4) Å, c = 13.0214(7) Å, V = 1590.30(14) Å 3, R1 = 0.020. Their framework crystal structures contain channels up to 11.62 × 10.54 Å filled by various alkali metals.

AB - To date, uranyl silicates are mostly represented by minerals in nature. However, their synthetic counterparts can be used as ion exchange materials. A new approach for the synthesis of framework uranyl silicates is reported. The new compounds Rb 2[(UO 2) 2(Si 8O 19)](H 2O) 2.5 ( 1), (K,Rb) 2[(UO 2)(Si 10O 22)] ( 2), [Rb 3Cl][(UO 2)(Si 4O 10)] ( 3) and [Cs 3Cl][(UO 2)(Si 4O 10)] ( 4) were prepared at harsh conditions in "activated" silica tubes at 900 °C. The activation of silica was performed using 40% hydrofluoric acid and lead oxide. Crystal structures of new uranyl silicates were solved by direct methods and refined: 1 is orthorhombic, Cmce, a = 14.5795(2) Å, b = 14.2083(2) Å, c = 23.1412(4) Å, V = 4793.70(13) Å 3, R1 = 0.023; 2 is monoclinic, C2/ m, a = 23.0027(8) Å, b = 8.0983(3) Å, c = 11.9736(4) Å, β = 90.372(3) °, V = 2230.43(14) Å 3, R1 = 0.034; 3 is orthorhombic, Imma, a = 15.2712(12) Å, b = 7.9647(8) Å, c = 12.4607(9) Å, V = 1515.6(2) Å 3, R1 = 0.035, 4 is orthorhombic, Imma, a = 15.4148(8) Å, b = 7.9229(4) Å, c = 13.0214(7) Å, V = 1590.30(14) Å 3, R1 = 0.020. Their framework crystal structures contain channels up to 11.62 × 10.54 Å filled by various alkali metals.

KW - inorganic synthesis

KW - microporous structures

KW - silicates

KW - uranyl compounds

UR - https://www.mendeley.com/catalogue/1cf48e08-781e-30a6-80bb-e4a1ca0ebfdc/

U2 - 10.3390/ma16114153

DO - 10.3390/ma16114153

M3 - Article

C2 - 37297289

VL - 16

JO - Materials

JF - Materials

SN - 1996-1944

IS - 11

M1 - 4153

ER -