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Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding. / Kryukova, Mariya A.; Ivanov, Daniil M.; Kinzhalov, Mikhail A.; Novikov, Alexander S.; Smirnov, Andrey S.; Bokach, Nadezhda A.; Yu. Kukushkin, Vadim.

In: Chemistry - A European Journal, Vol. 25, No. 60, 28.10.2019, p. 13671-13675.

Research output: Contribution to journal › Article › peer-review

Harvard

Kryukova, MA, Ivanov, DM, Kinzhalov, MA, Novikov, AS, Smirnov, AS, Bokach, NA & Yu. Kukushkin, V 2019, 'Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding', Chemistry - A European Journal, vol. 25, no. 60, pp. 13671-13675. https://doi.org/10.1002/chem.201902264

APA

Kryukova, M. A., Ivanov, D. M., Kinzhalov, M. A., Novikov, A. S., Smirnov, A. S., Bokach, N. A., & Yu. Kukushkin, V. (2019). Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding. Chemistry - A European Journal, 25(60), 13671-13675. https://doi.org/10.1002/chem.201902264

Vancouver

Kryukova MA, Ivanov DM, Kinzhalov MA, Novikov AS, Smirnov AS, Bokach NA et al. Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding. Chemistry - A European Journal. 2019 Oct 28;25(60):13671-13675. https://doi.org/10.1002/chem.201902264

Author

Kryukova, Mariya A. ; Ivanov, Daniil M. ; Kinzhalov, Mikhail A. ; Novikov, Alexander S. ; Smirnov, Andrey S. ; Bokach, Nadezhda A. ; Yu. Kukushkin, Vadim. / Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding. In: Chemistry - A European Journal. 2019 ; Vol. 25, No. 60. pp. 13671-13675.

BibTeX

@article{2b97da354af642b691d39732207b6e43,
title = "Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding",
abstract = "The isocyanide trans-[PdBr2(CNC6H4-4-X′)2] (X′=Br, I) and nitrile trans-[PtX2(NCC6H4-4-X′)2] (X/X′=Cl/Cl, Cl/Br, Br/Cl, Br/Br) complexes exhibit similar structural motif in the solid state, which is determined by hitherto unreported four-center nodes formed by cyclic halogen bonding. Each node is built up by four Type II C−X′⋅⋅⋅X−M halogen-bonding contacts and include one Type I M−X⋅⋅⋅X−M interaction, thus giving the rhombic-like structure. These nodes serve as supramolecular synthons to form 2D layers or double chains of molecules linked by a halogen bond. Results of DFT calculations indicate that all contacts within the nodes are typical noncovalent interactions with the estimated strengths in the range 0.6–2.9 kcal mol−1.",
keywords = "crystal engineering, four-center nodes, halogen bonding, noncovalent interactions, supramolecular synthons, ACTIVATION, CRYSTAL-STRUCTURE, COMPLEXES, CL, NONCOVALENT INTERACTIONS, SOLID-STATE, BR, CHEMISTRY, M-X, INTERMOLECULAR INTERACTIONS",
author = "Kryukova, {Mariya A.} and Ivanov, {Daniil M.} and Kinzhalov, {Mikhail A.} and Novikov, {Alexander S.} and Smirnov, {Andrey S.} and Bokach, {Nadezhda A.} and {Yu. Kukushkin}, Vadim",
year = "2019",
month = oct,
day = "28",
doi = "10.1002/chem.201902264",
language = "English",
volume = "25",
pages = "13671--13675",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "60",

}

RIS

TY - JOUR

T1 - Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding

AU - Kryukova, Mariya A.

AU - Ivanov, Daniil M.

AU - Kinzhalov, Mikhail A.

AU - Novikov, Alexander S.

AU - Smirnov, Andrey S.

AU - Bokach, Nadezhda A.

AU - Yu. Kukushkin, Vadim

PY - 2019/10/28

Y1 - 2019/10/28

N2 - The isocyanide trans-[PdBr2(CNC6H4-4-X′)2] (X′=Br, I) and nitrile trans-[PtX2(NCC6H4-4-X′)2] (X/X′=Cl/Cl, Cl/Br, Br/Cl, Br/Br) complexes exhibit similar structural motif in the solid state, which is determined by hitherto unreported four-center nodes formed by cyclic halogen bonding. Each node is built up by four Type II C−X′⋅⋅⋅X−M halogen-bonding contacts and include one Type I M−X⋅⋅⋅X−M interaction, thus giving the rhombic-like structure. These nodes serve as supramolecular synthons to form 2D layers or double chains of molecules linked by a halogen bond. Results of DFT calculations indicate that all contacts within the nodes are typical noncovalent interactions with the estimated strengths in the range 0.6–2.9 kcal mol−1.

AB - The isocyanide trans-[PdBr2(CNC6H4-4-X′)2] (X′=Br, I) and nitrile trans-[PtX2(NCC6H4-4-X′)2] (X/X′=Cl/Cl, Cl/Br, Br/Cl, Br/Br) complexes exhibit similar structural motif in the solid state, which is determined by hitherto unreported four-center nodes formed by cyclic halogen bonding. Each node is built up by four Type II C−X′⋅⋅⋅X−M halogen-bonding contacts and include one Type I M−X⋅⋅⋅X−M interaction, thus giving the rhombic-like structure. These nodes serve as supramolecular synthons to form 2D layers or double chains of molecules linked by a halogen bond. Results of DFT calculations indicate that all contacts within the nodes are typical noncovalent interactions with the estimated strengths in the range 0.6–2.9 kcal mol−1.

KW - crystal engineering

KW - four-center nodes

KW - halogen bonding

KW - noncovalent interactions

KW - supramolecular synthons

KW - ACTIVATION

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - CL

KW - NONCOVALENT INTERACTIONS

KW - SOLID-STATE

KW - BR

KW - CHEMISTRY

KW - M-X

KW - INTERMOLECULAR INTERACTIONS

UR - http://www.scopus.com/inward/record.url?scp=85071625872&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/fourcenter-nodes-supramolecular-synthons-based-cyclic-halogen-bonding

U2 - 10.1002/chem.201902264

DO - 10.1002/chem.201902264

M3 - Article

AN - SCOPUS:85071625872

VL - 25

SP - 13671

EP - 13675

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 60

ER -

ID: 46255577