Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles

Research output: Contribution to journal › Article › peer-review

DOI

https://doi.org/10.1134/S1070363218100158
Final published version

The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl ₂(CNXyl) ₂], Xyl = 2,6-Me ₂C ₆H ₃) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.

Original language	English
Pages (from-to)	2119–2124
Number of pages	6
Journal	Russian Journal of General Chemistry
Volume	88
Issue number	10
DOIs	https://doi.org/10.1134/S1070363218100158
State	Published - 1 Oct 2018

Scopus subject areas

Inorganic Chemistry
Chemistry(all)

Research areas

aminothiazaheterocycles, heteronuclear carbene complexes, isocyanide ligands, palladium(II) diaminocarbene complexes, platinum(II) diaminocarbene complexes, SONOGASHIRA, LIGANDS, ACYCLIC DIAMINOCARBENE COMPLEXES, COPPER-FREE, ISONITRILES, EFFICIENT CATALYSTS, GOLD(I)

ID: 35457198