Formation of a new adduct based on fullerene tris-malonate samarium salt С60–[C60(=C(COO)2)3]Sm2

Formation of a new adduct based on fullerene tris-malonate samarium salt С₆₀–[C₆₀(=C(COO)₂)₃]Sm₂

Research output: Contribution to journal › Article › peer-review

Department of Solid State Chemistry

DOI

https://doi.org/10.1134/S0036024417030207
Final published version

A. A. Petrov
V. A. Keskinov
K. N. Semenov
N. A. Charykov
D. G. Letenko
V. A. Nikitin

Gram quantities of a new adduct based on light fullerene tris-malonate samarium salt С₆₀ [C₆₀(=C(COO)₂)₃]Sm₂ are obtained via the reaction of ion exchange. The obtained adduct is studied by means of electron and infrared spectroscopy, X-ray and elemental analysis, electron microscopy, and thermogravimetry. The polythermal solubility of [C₆₀(=C(COO)₂)₃]Sm₂ in water is determined in ampoules via saturation within 20–70°C. The composition of crystalline hydrate [C₆₀(=C(COO)₂)₃]Sm₂ · 36Н₂О, which exists in equilibrium with the saturated solution, is estimated.

Original language	English
Pages (from-to)	549-554
Number of pages	6
Journal	Russian Journal of Physical Chemistry A
Volume	91
Issue number	3
DOIs	https://doi.org/10.1134/S0036024417030207
State	Published - 1 Mar 2017

Research areas

electron and infrared spectroscopy, electron microscopy, solubility in water, thermogravimetry, X-ray and elemental analysis, С tris-malonate samarium salt

Scopus subject areas

Physical and Theoretical Chemistry

ID: 88053913