Research output: Contribution to journal › Article › peer-review
Formation and thermodynamics of gaseous germanium and tin vanadates: A mass spectrometric and quantum chemical study. / Shugurov, S.M.; Panin, A.I.; Lopatin, S.I.; Emelyanova, K.A.
In: Dalton Transactions, Vol. 44, No. 21, 2015, p. 10014-10021.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Formation and thermodynamics of gaseous germanium and tin vanadates: A mass spectrometric and quantum chemical study
AU - Shugurov, S.M.
AU - Panin, A.I.
AU - Lopatin, S.I.
AU - Emelyanova, K.A.
PY - 2015
Y1 - 2015
N2 - © The Royal Society of Chemistry.The stabilities of gaseous germanium and tin vanadates were confirmed by high temperature mass spectrometry, and its structures were determined by quantum chemical calculations. A number of gas-phase reactions involving these gaseous salts were studied. On the basis of the equilibrium constants, the standard formation enthalpies of gaseous GeV2O6 (-1520 ± 42 kJ mol-1) and SnV2O6 (-1520 ± 43 kJ mol-1) were determined at a temperature of 298 K.
AB - © The Royal Society of Chemistry.The stabilities of gaseous germanium and tin vanadates were confirmed by high temperature mass spectrometry, and its structures were determined by quantum chemical calculations. A number of gas-phase reactions involving these gaseous salts were studied. On the basis of the equilibrium constants, the standard formation enthalpies of gaseous GeV2O6 (-1520 ± 42 kJ mol-1) and SnV2O6 (-1520 ± 43 kJ mol-1) were determined at a temperature of 298 K.
U2 - 10.1039/c5dt00660k
DO - 10.1039/c5dt00660k
M3 - Article
VL - 44
SP - 10014
EP - 10021
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 21
ER -
ID: 4008118