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Formation and thermodynamics of gaseous germanium and tin vanadates: A mass spectrometric and quantum chemical study. / Shugurov, S.M.; Panin, A.I.; Lopatin, S.I.; Emelyanova, K.A.

In: Dalton Transactions, Vol. 44, No. 21, 2015, p. 10014-10021.

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@article{027785e2143c41f1a09a1978ed963aed,
title = "Formation and thermodynamics of gaseous germanium and tin vanadates: A mass spectrometric and quantum chemical study",
abstract = "{\textcopyright} The Royal Society of Chemistry.The stabilities of gaseous germanium and tin vanadates were confirmed by high temperature mass spectrometry, and its structures were determined by quantum chemical calculations. A number of gas-phase reactions involving these gaseous salts were studied. On the basis of the equilibrium constants, the standard formation enthalpies of gaseous GeV2O6 (-1520 ± 42 kJ mol-1) and SnV2O6 (-1520 ± 43 kJ mol-1) were determined at a temperature of 298 K.",
author = "S.M. Shugurov and A.I. Panin and S.I. Lopatin and K.A. Emelyanova",
year = "2015",
doi = "10.1039/c5dt00660k",
language = "English",
volume = "44",
pages = "10014--10021",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "21",

}

RIS

TY - JOUR

T1 - Formation and thermodynamics of gaseous germanium and tin vanadates: A mass spectrometric and quantum chemical study

AU - Shugurov, S.M.

AU - Panin, A.I.

AU - Lopatin, S.I.

AU - Emelyanova, K.A.

PY - 2015

Y1 - 2015

N2 - © The Royal Society of Chemistry.The stabilities of gaseous germanium and tin vanadates were confirmed by high temperature mass spectrometry, and its structures were determined by quantum chemical calculations. A number of gas-phase reactions involving these gaseous salts were studied. On the basis of the equilibrium constants, the standard formation enthalpies of gaseous GeV2O6 (-1520 ± 42 kJ mol-1) and SnV2O6 (-1520 ± 43 kJ mol-1) were determined at a temperature of 298 K.

AB - © The Royal Society of Chemistry.The stabilities of gaseous germanium and tin vanadates were confirmed by high temperature mass spectrometry, and its structures were determined by quantum chemical calculations. A number of gas-phase reactions involving these gaseous salts were studied. On the basis of the equilibrium constants, the standard formation enthalpies of gaseous GeV2O6 (-1520 ± 42 kJ mol-1) and SnV2O6 (-1520 ± 43 kJ mol-1) were determined at a temperature of 298 K.

U2 - 10.1039/c5dt00660k

DO - 10.1039/c5dt00660k

M3 - Article

VL - 44

SP - 10014

EP - 10021

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 21

ER -

ID: 4008118