Fluorescent core-shell polymer particles containing luminophore dyes

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Fluorescent core-shell polymer particles containing luminophore dyes : synthesis and optical response to acetone. / Shevchenko, Natalia; Pankova, Galina; Shabsels, Boris; Baigildin, Vadim; Khoshkin, Alexander; Ukleev, Timofei; Sel’kin, Alexander.

In: Journal of Dispersion Science and Technology, Vol. 40, No. 6, 03.06.2019, p. 802-810.

Research output: Contribution to journal › Article › peer-review

Author

Shevchenko, Natalia ; Pankova, Galina ; Shabsels, Boris ; Baigildin, Vadim ; Khoshkin, Alexander ; Ukleev, Timofei ; Sel’kin, Alexander. / Fluorescent core-shell polymer particles containing luminophore dyes : synthesis and optical response to acetone. In: Journal of Dispersion Science and Technology. 2019 ; Vol. 40, No. 6. pp. 802-810.

BibTeX

@article{afc04845af2b44bfbb35cd06560a576b,

title = "Fluorescent core-shell polymer particles containing luminophore dyes: synthesis and optical response to acetone",

abstract = "Monodisperse dye-containing crosslinked particles are promising for application in novel optical chemical sensors due to their intrinsic sensitivity. However, preparation of these particles in aqueous media still remains a challenge, since luminophores inhibit radical processes or else cannot embed into polymer chains because of difference in monomer reactivity ratios. In this work, novel dye-containing monodisperse crosslinked particles were prepared and characterized. In order to obtain dye-containing monodisperse crosslinked particles, we studied seed copolymerization of styrene in the presence of divinylbenzene. The influence of nature and concentration of the used comonomers and co-solvents on shape, size distributions and surface characteristics of the particles formed was investigated. Shapes and diameters of the particles were analyzed by DLS, TEM and SEM. The data of SEM and optical spectroscopy studies demonstrated that the synthesized particles were able to self-assemble into thin-film three-dimensional ordered structures. Finally, the structures under study are promising for development of sensor devices with optical response to acetone.",

keywords = "Acetone, crosslinking, dye-containing particles, sensory materials",

author = "Natalia Shevchenko and Galina Pankova and Boris Shabsels and Vadim Baigildin and Alexander Khoshkin and Timofei Ukleev and Alexander Sel{\textquoteright}kin",

year = "2019",

month = jun,

day = "3",

doi = "10.1080/01932691.2018.1480389",

language = "English",

volume = "40",

pages = "802--810",

journal = "Journal of Dispersion Science and Technology",

issn = "0193-2691",

publisher = "Taylor & Francis",

number = "6",

}

RIS

TY - JOUR

T1 - Fluorescent core-shell polymer particles containing luminophore dyes

T2 - synthesis and optical response to acetone

AU - Shevchenko, Natalia

AU - Pankova, Galina

AU - Shabsels, Boris

AU - Baigildin, Vadim

AU - Khoshkin, Alexander

AU - Ukleev, Timofei

AU - Sel’kin, Alexander

PY - 2019/6/3

Y1 - 2019/6/3

N2 - Monodisperse dye-containing crosslinked particles are promising for application in novel optical chemical sensors due to their intrinsic sensitivity. However, preparation of these particles in aqueous media still remains a challenge, since luminophores inhibit radical processes or else cannot embed into polymer chains because of difference in monomer reactivity ratios. In this work, novel dye-containing monodisperse crosslinked particles were prepared and characterized. In order to obtain dye-containing monodisperse crosslinked particles, we studied seed copolymerization of styrene in the presence of divinylbenzene. The influence of nature and concentration of the used comonomers and co-solvents on shape, size distributions and surface characteristics of the particles formed was investigated. Shapes and diameters of the particles were analyzed by DLS, TEM and SEM. The data of SEM and optical spectroscopy studies demonstrated that the synthesized particles were able to self-assemble into thin-film three-dimensional ordered structures. Finally, the structures under study are promising for development of sensor devices with optical response to acetone.

AB - Monodisperse dye-containing crosslinked particles are promising for application in novel optical chemical sensors due to their intrinsic sensitivity. However, preparation of these particles in aqueous media still remains a challenge, since luminophores inhibit radical processes or else cannot embed into polymer chains because of difference in monomer reactivity ratios. In this work, novel dye-containing monodisperse crosslinked particles were prepared and characterized. In order to obtain dye-containing monodisperse crosslinked particles, we studied seed copolymerization of styrene in the presence of divinylbenzene. The influence of nature and concentration of the used comonomers and co-solvents on shape, size distributions and surface characteristics of the particles formed was investigated. Shapes and diameters of the particles were analyzed by DLS, TEM and SEM. The data of SEM and optical spectroscopy studies demonstrated that the synthesized particles were able to self-assemble into thin-film three-dimensional ordered structures. Finally, the structures under study are promising for development of sensor devices with optical response to acetone.

KW - Acetone

KW - crosslinking

KW - dye-containing particles

KW - sensory materials

UR - http://www.scopus.com/inward/record.url?scp=85051785366&partnerID=8YFLogxK

U2 - 10.1080/01932691.2018.1480389

DO - 10.1080/01932691.2018.1480389

M3 - Article

AN - SCOPUS:85051785366

VL - 40

SP - 802

EP - 810

JO - Journal of Dispersion Science and Technology

JF - Journal of Dispersion Science and Technology

SN - 0193-2691

IS - 6

ER -

ID: 50669844