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Flow birefringence of pullulan molecules in solutions. / Pavlov, Georges M.; Yevlampieva, Natalia P.; Korneeva, Evgueniya V.

In: Polymer, Vol. 39, No. 1, 01.01.1998, p. 235-239.

Research output: Contribution to journal › Article › peer-review

Harvard

Pavlov, GM, Yevlampieva, NP & Korneeva, EV 1998, 'Flow birefringence of pullulan molecules in solutions', Polymer, vol. 39, no. 1, pp. 235-239. https://doi.org/10.1016/S0032-3861(97)84843-4

APA

Pavlov, G. M., Yevlampieva, N. P., & Korneeva, E. V. (1998). Flow birefringence of pullulan molecules in solutions. Polymer, 39(1), 235-239. https://doi.org/10.1016/S0032-3861(97)84843-4

Vancouver

Pavlov GM, Yevlampieva NP, Korneeva EV. Flow birefringence of pullulan molecules in solutions. Polymer. 1998 Jan 1;39(1):235-239. https://doi.org/10.1016/S0032-3861(97)84843-4

Author

Pavlov, Georges M. ; Yevlampieva, Natalia P. ; Korneeva, Evgueniya V. / Flow birefringence of pullulan molecules in solutions. In: Polymer. 1998 ; Vol. 39, No. 1. pp. 235-239.

BibTeX

@article{2950c2237bcc4cd0b6bf2ea71ea19e77,
title = "Flow birefringence of pullulan molecules in solutions",
abstract = "Flow birefringence (FB) of polymaltotriose (pullulan) in water and in dimethylsulfoxide (DMSO) has been studied. Pullulan has a high refractive index increment (Δn/Δc) in water but in DMSO it is low. Accordingly, in water the FB of molecules is mainly determined by the macroform effect and in DMSO by the intrinsic anisotropy of polarizabilities of the polysaccharide chain. The analysis of the dependencies of reduced FB values [n]/[η] on molecular weight and on Δn/Δc makes it possible to determine quantitatively the value of intrinsic segmental anisotropy of pullulan molecules: (α1 - α2) = +33 × 10-25 cm3. On the basis of this value the optical anisotropy of the glucopyranose ring was determined. {\textcopyright} 1997 Published by Elsevier Science Ltd.",
keywords = "Flow birefringence, Linear polysaccharide, Optical anisotropy",
author = "Pavlov, {Georges M.} and Yevlampieva, {Natalia P.} and Korneeva, {Evgueniya V.}",
year = "1998",
month = jan,
day = "1",
doi = "10.1016/S0032-3861(97)84843-4",
language = "English",
volume = "39",
pages = "235--239",
journal = "Polymer",
issn = "0032-3861",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Flow birefringence of pullulan molecules in solutions

AU - Pavlov, Georges M.

AU - Yevlampieva, Natalia P.

AU - Korneeva, Evgueniya V.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Flow birefringence (FB) of polymaltotriose (pullulan) in water and in dimethylsulfoxide (DMSO) has been studied. Pullulan has a high refractive index increment (Δn/Δc) in water but in DMSO it is low. Accordingly, in water the FB of molecules is mainly determined by the macroform effect and in DMSO by the intrinsic anisotropy of polarizabilities of the polysaccharide chain. The analysis of the dependencies of reduced FB values [n]/[η] on molecular weight and on Δn/Δc makes it possible to determine quantitatively the value of intrinsic segmental anisotropy of pullulan molecules: (α1 - α2) = +33 × 10-25 cm3. On the basis of this value the optical anisotropy of the glucopyranose ring was determined. © 1997 Published by Elsevier Science Ltd.

AB - Flow birefringence (FB) of polymaltotriose (pullulan) in water and in dimethylsulfoxide (DMSO) has been studied. Pullulan has a high refractive index increment (Δn/Δc) in water but in DMSO it is low. Accordingly, in water the FB of molecules is mainly determined by the macroform effect and in DMSO by the intrinsic anisotropy of polarizabilities of the polysaccharide chain. The analysis of the dependencies of reduced FB values [n]/[η] on molecular weight and on Δn/Δc makes it possible to determine quantitatively the value of intrinsic segmental anisotropy of pullulan molecules: (α1 - α2) = +33 × 10-25 cm3. On the basis of this value the optical anisotropy of the glucopyranose ring was determined. © 1997 Published by Elsevier Science Ltd.

KW - Flow birefringence

KW - Linear polysaccharide

KW - Optical anisotropy

UR - http://www.scopus.com/inward/record.url?scp=0031952508&partnerID=8YFLogxK

U2 - 10.1016/S0032-3861(97)84843-4

DO - 10.1016/S0032-3861(97)84843-4

M3 - Article

AN - SCOPUS:0031952508

VL - 39

SP - 235

EP - 239

JO - Polymer

JF - Polymer

SN - 0032-3861

IS - 1

ER -

ID: 132314616