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Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations : Structures, thermal stability and features of halogen⋯halogen contacts in solid state. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Plyusnin, Pavel E.; Korolkov, Ilya V.; Sokolov, Maxim N.; Fedin, Vladimir P.

In: Inorganica Chimica Acta, Vol. 502, 119278, 01.01.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Adonin, SA, Bondarenko, MA, Novikov, AS, Plyusnin, PE, Korolkov, IV, Sokolov, MN & Fedin, VP 2019, 'Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state', Inorganica Chimica Acta, vol. 502, 119278. https://doi.org/10.1016/j.ica.2019.119278

APA

Adonin, S. A., Bondarenko, M. A., Novikov, A. S., Plyusnin, P. E., Korolkov, I. V., Sokolov, M. N., & Fedin, V. P. (Accepted/In press). Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state. Inorganica Chimica Acta, 502, [119278]. https://doi.org/10.1016/j.ica.2019.119278

Vancouver

Adonin SA, Bondarenko MA, Novikov AS, Plyusnin PE, Korolkov IV, Sokolov MN et al. Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state. Inorganica Chimica Acta. 2019 Jan 1;502. 119278. https://doi.org/10.1016/j.ica.2019.119278

Author

Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Novikov, Alexander S. ; Plyusnin, Pavel E. ; Korolkov, Ilya V. ; Sokolov, Maxim N. ; Fedin, Vladimir P. / Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations : Structures, thermal stability and features of halogen⋯halogen contacts in solid state. In: Inorganica Chimica Acta. 2019 ; Vol. 502.

BibTeX

@article{3cb1a1cd685e433493c9af7d5edba00c,
title = "Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state",
abstract = "Reactions of Sb2O3 solution in HBr in presence of Br2 with series of pyridinium-type cation salts resulted in formation of Cat[SbBr6] (Cat = 1,3,4-MePy+ (1) and 1,4-MePy+ (2)) and Cat2{[SbBr6](Br3)} (Cat = 1,2-MePy+ (3), 1-Et-2-MePy+ (4) and 1-Et-4-MePy+ (5)) complexes which were characterized by X-ray diffractometry. For all compounds, thermal stability was investigated by TGA method; energies of non-covalent Br⋯Br interactions were estimated by DFT calculations and QTAIM analysis (M06/DZP-DKH level of theory).",
keywords = "Antimony, Halide complexes, Halogen bonding, Polyhalogens, Supramolecular contacts",
author = "Adonin, {Sergey A.} and Bondarenko, {Mikhail A.} and Novikov, {Alexander S.} and Plyusnin, {Pavel E.} and Korolkov, {Ilya V.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1016/j.ica.2019.119278",
language = "English",
volume = "502",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations

T2 - Structures, thermal stability and features of halogen⋯halogen contacts in solid state

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Plyusnin, Pavel E.

AU - Korolkov, Ilya V.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Reactions of Sb2O3 solution in HBr in presence of Br2 with series of pyridinium-type cation salts resulted in formation of Cat[SbBr6] (Cat = 1,3,4-MePy+ (1) and 1,4-MePy+ (2)) and Cat2{[SbBr6](Br3)} (Cat = 1,2-MePy+ (3), 1-Et-2-MePy+ (4) and 1-Et-4-MePy+ (5)) complexes which were characterized by X-ray diffractometry. For all compounds, thermal stability was investigated by TGA method; energies of non-covalent Br⋯Br interactions were estimated by DFT calculations and QTAIM analysis (M06/DZP-DKH level of theory).

AB - Reactions of Sb2O3 solution in HBr in presence of Br2 with series of pyridinium-type cation salts resulted in formation of Cat[SbBr6] (Cat = 1,3,4-MePy+ (1) and 1,4-MePy+ (2)) and Cat2{[SbBr6](Br3)} (Cat = 1,2-MePy+ (3), 1-Et-2-MePy+ (4) and 1-Et-4-MePy+ (5)) complexes which were characterized by X-ray diffractometry. For all compounds, thermal stability was investigated by TGA method; energies of non-covalent Br⋯Br interactions were estimated by DFT calculations and QTAIM analysis (M06/DZP-DKH level of theory).

KW - Antimony

KW - Halide complexes

KW - Halogen bonding

KW - Polyhalogens

KW - Supramolecular contacts

UR - http://www.scopus.com/inward/record.url?scp=85075854928&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.119278

DO - 10.1016/j.ica.2019.119278

M3 - Article

AN - SCOPUS:85075854928

VL - 502

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119278

ER -

ID: 50513473