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First example of a click-reaction on the aminate copper complexes : effect of reaction parameters. / Esarev, Igor V.; Gurzhiy, Vladislav V.; Selyutin, Artem A.; Laptenkova, Anastasia V.; Poddel'sky, Andrey I.; Medvedskiy, Nicolay L.; Ponyaev, Alexander I.; Trifonov, Rostislav E.; Eremin, Alexey V.

In: Mendeleev Communications, Vol. 28, No. 6, 01.11.2018, p. 606-608.

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Esarev, Igor V. ; Gurzhiy, Vladislav V. ; Selyutin, Artem A. ; Laptenkova, Anastasia V. ; Poddel'sky, Andrey I. ; Medvedskiy, Nicolay L. ; Ponyaev, Alexander I. ; Trifonov, Rostislav E. ; Eremin, Alexey V. / First example of a click-reaction on the aminate copper complexes : effect of reaction parameters. In: Mendeleev Communications. 2018 ; Vol. 28, No. 6. pp. 606-608.

BibTeX

@article{7b2added19014bff82dfe7e20d5313e2,
title = "First example of a click-reaction on the aminate copper complexes: effect of reaction parameters",
abstract = "The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.",
author = "Esarev, {Igor V.} and Gurzhiy, {Vladislav V.} and Selyutin, {Artem A.} and Laptenkova, {Anastasia V.} and Poddel'sky, {Andrey I.} and Medvedskiy, {Nicolay L.} and Ponyaev, {Alexander I.} and Trifonov, {Rostislav E.} and Eremin, {Alexey V.}",
year = "2018",
month = nov,
day = "1",
doi = "10.1016/j.mencom.2018.11.014",
language = "English",
volume = "28",
pages = "606--608",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - First example of a click-reaction on the aminate copper complexes

T2 - effect of reaction parameters

AU - Esarev, Igor V.

AU - Gurzhiy, Vladislav V.

AU - Selyutin, Artem A.

AU - Laptenkova, Anastasia V.

AU - Poddel'sky, Andrey I.

AU - Medvedskiy, Nicolay L.

AU - Ponyaev, Alexander I.

AU - Trifonov, Rostislav E.

AU - Eremin, Alexey V.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

AB - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

UR - http://www.scopus.com/inward/record.url?scp=85057582995&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2018.11.014

DO - 10.1016/j.mencom.2018.11.014

M3 - Article

AN - SCOPUS:85057582995

VL - 28

SP - 606

EP - 608

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 6

ER -

ID: 35404885