Research output: Contribution to journal › Article › peer-review
First example of a click-reaction on the aminate copper complexes : effect of reaction parameters. / Esarev, Igor V.; Gurzhiy, Vladislav V.; Selyutin, Artem A.; Laptenkova, Anastasia V.; Poddel'sky, Andrey I.; Medvedskiy, Nicolay L.; Ponyaev, Alexander I.; Trifonov, Rostislav E.; Eremin, Alexey V.
In: Mendeleev Communications, Vol. 28, No. 6, 01.11.2018, p. 606-608.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - First example of a click-reaction on the aminate copper complexes
T2 - effect of reaction parameters
AU - Esarev, Igor V.
AU - Gurzhiy, Vladislav V.
AU - Selyutin, Artem A.
AU - Laptenkova, Anastasia V.
AU - Poddel'sky, Andrey I.
AU - Medvedskiy, Nicolay L.
AU - Ponyaev, Alexander I.
AU - Trifonov, Rostislav E.
AU - Eremin, Alexey V.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.
AB - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.
UR - http://www.scopus.com/inward/record.url?scp=85057582995&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2018.11.014
DO - 10.1016/j.mencom.2018.11.014
M3 - Article
AN - SCOPUS:85057582995
VL - 28
SP - 606
EP - 608
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 6
ER -
ID: 35404885