Standard

Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I). / Ding, X.; Tuikka, M.J.; Hirva, P.; Kukushkin, V.Y.; Novikov, A.S.; Haukka, M.

In: CrystEngComm, Vol. 18, No. 11, 2016, p. 1987-1995.

Research output: Contribution to journal › Article › peer-review

Harvard

Ding, X, Tuikka, MJ, Hirva, P, Kukushkin, VY, Novikov, AS & Haukka, M 2016, 'Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I)', CrystEngComm, vol. 18, no. 11, pp. 1987-1995. https://doi.org/10.1039/c5ce02396c, https://doi.org/10.1039/c5ce02396c

APA

Ding, X., Tuikka, M. J., Hirva, P., Kukushkin, V. Y., Novikov, A. S., & Haukka, M. (2016). Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I). CrystEngComm, 18(11), 1987-1995. https://doi.org/10.1039/c5ce02396c, https://doi.org/10.1039/c5ce02396c

Vancouver

Ding X, Tuikka MJ, Hirva P, Kukushkin VY, Novikov AS, Haukka M. Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I). CrystEngComm. 2016;18(11):1987-1995. https://doi.org/10.1039/c5ce02396c, https://doi.org/10.1039/c5ce02396c

Author

Ding, X. ; Tuikka, M.J. ; Hirva, P. ; Kukushkin, V.Y. ; Novikov, A.S. ; Haukka, M. / Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I). In: CrystEngComm. 2016 ; Vol. 18, No. 11. pp. 1987-1995.

BibTeX

@article{ca1e66dc2ce44b60826490d68416744c,
title = "Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I)",
abstract = "{\textcopyright} 2016 The Royal Society of Chemistry. The current paper introduces the use of carbonyl containing ruthenium complexes, [Ru(bpy)(CO)2X2] (X = Cl, Br, I), as halogen bond acceptors for a I2 halogen bond donor. In all structures, the metal coordinated halogenido ligand acts as the actual halogen bond acceptor. Diiodine, I2, molecules are connected to the metal complexes through both ends of the molecule forming bridges between the complexes. Due to the charge transfer from Ru-X to I2, formation of the first Ru-X⋯I2 contact tends to generate a negative charge on I2 and redistribute the electron density anisotropically. If the initial Ru-X⋯IA-IB interaction causes a notable change in the electron density of I2, the increased negative charge accumulates on the second iodine, IB. The increased negative charge on IB reduces its ability to act as a halogen bond donor. With the [Ru(bpy)(CO)2Cl2] complex, the electron density of the I2 molecule remains isotropic and it acts as a symmetrical halogen bond donor for two m",
author = "X. Ding and M.J. Tuikka and P. Hirva and V.Y. Kukushkin and A.S. Novikov and M. Haukka",
note = "cited By 14",
year = "2016",
doi = "10.1039/c5ce02396c",
language = "English",
volume = "18",
pages = "1987--1995",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "11",

}

RIS

TY - JOUR

T1 - Fine-tuning halogen bonding properties of diiodine through halogen-halogen charge transfer-extended [Ru(2,2′-bipyridine)(CO)2X2]·I2 systems (X = Cl, Br, I)

AU - Ding, X.

AU - Tuikka, M.J.

AU - Hirva, P.

AU - Kukushkin, V.Y.

AU - Novikov, A.S.

AU - Haukka, M.

N1 - cited By 14

PY - 2016

Y1 - 2016

N2 - © 2016 The Royal Society of Chemistry. The current paper introduces the use of carbonyl containing ruthenium complexes, [Ru(bpy)(CO)2X2] (X = Cl, Br, I), as halogen bond acceptors for a I2 halogen bond donor. In all structures, the metal coordinated halogenido ligand acts as the actual halogen bond acceptor. Diiodine, I2, molecules are connected to the metal complexes through both ends of the molecule forming bridges between the complexes. Due to the charge transfer from Ru-X to I2, formation of the first Ru-X⋯I2 contact tends to generate a negative charge on I2 and redistribute the electron density anisotropically. If the initial Ru-X⋯IA-IB interaction causes a notable change in the electron density of I2, the increased negative charge accumulates on the second iodine, IB. The increased negative charge on IB reduces its ability to act as a halogen bond donor. With the [Ru(bpy)(CO)2Cl2] complex, the electron density of the I2 molecule remains isotropic and it acts as a symmetrical halogen bond donor for two m

AB - © 2016 The Royal Society of Chemistry. The current paper introduces the use of carbonyl containing ruthenium complexes, [Ru(bpy)(CO)2X2] (X = Cl, Br, I), as halogen bond acceptors for a I2 halogen bond donor. In all structures, the metal coordinated halogenido ligand acts as the actual halogen bond acceptor. Diiodine, I2, molecules are connected to the metal complexes through both ends of the molecule forming bridges between the complexes. Due to the charge transfer from Ru-X to I2, formation of the first Ru-X⋯I2 contact tends to generate a negative charge on I2 and redistribute the electron density anisotropically. If the initial Ru-X⋯IA-IB interaction causes a notable change in the electron density of I2, the increased negative charge accumulates on the second iodine, IB. The increased negative charge on IB reduces its ability to act as a halogen bond donor. With the [Ru(bpy)(CO)2Cl2] complex, the electron density of the I2 molecule remains isotropic and it acts as a symmetrical halogen bond donor for two m

U2 - 10.1039/c5ce02396c

DO - 10.1039/c5ce02396c

M3 - Article

VL - 18

SP - 1987

EP - 1995

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 11

ER -

ID: 7927567